Photoinduced Spin Centers in Photocatalytic Metal–Organic Framework UiO‐66

Abstract Metal–Organic frameworks (MOFs) are promising candidates for advanced photocatalytically active materials. These porous crystalline compounds have large active surface areas and structural tunability and are thus highly competitive with oxides, the well‐established material class for photocatalysis. However, due to their complex organic and coordination chemistry composition, photophysical mechanisms involved in the photocatalytic processes in MOFs are still not well understood. Employing electron paramagnetic resonance (EPR) spectroscopy and time‐resolved photoluminescence spectroscopy (trPL), the fundamental processes of electron and hole generation are investigated, as well as capture events that lead to the formation of various radical species in UiO‐66, an archetypical MOF photocatalyst. A manifold of photoinduced electron spin centers is detected, which is subsequently analyzed and identified with the help of density‐functional theory (DFT) calculations. Under UV illumination, the symmetry, g‐tensors, and lifetimes of three distinct contributions are revealed: a surface O₂‐radical, a light‐induced electron‐hole pair, and a triplet exciton. Notably, the latter is found to emit (delayed) fluorescence. The findings provide new insights into the photoinduced charge transfer processes, which are the basis of photocatalytic activity in UiO‐66. This sets the stage for further studies on photogenerated spin centers in this and similar MOF materials.