journal article·2024-12Open access

Metal–Organic Frameworks Photocatalyst Through Plasmon‐Induced Hot‐Electrons

Tolga Zorlu, I. Brian Becerril‐Castro, Ana Sousa‐Castillo, Begoña Puértolas, Lucas V. Besteiro, Zhiming Wang, Alexander Govorov, Miguel A. Correa‐Duarte, Ramon A. Alvarez‐Puebla

Advanced Functional Materials· Volume 34· Issue 51

Abstract

Abstract Plasmonic metal–organic frameworks (plasmonic‐MOFs) ingeniously meld the homogeneous and vast porosity of MOFs with the distinctive plasmonic characteristics of metallic nanoparticles (NPs), creating a powerful synergy. This innovative combination is leveraged for enhanced plasmon‐induced hot‐electron photocatalysis, particularly within polystyrene beads adorned with silver nanoparticles (AgNPs) and encapsulated by zeolitic imidazolate framework‐8 (ZIF‐8). The strategic incorporation of AgNPs into this composite material generates hot carriers, significantly enhancing the catalytic performance of ZIF‐8. This approach not only exemplifies the potential for advanced photocatalytic processes of MOFs, but also paves the way for groundbreaking applications in environmental remediation and sustainable chemistry.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Advanced Nanomaterials in Catalysis · Gold and Silver Nanoparticles Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Physical and Inorganic Chemistry Universitat Rovira i Virgili Tarragona 43007 Spain

CINBIO Universidade de Vigo Vigo 36310 Spain

Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of China Chengdu 610054 China

Department of Physics and Astronomy Ohio University Athens OH 45701 USA

ICREA—Institució Catalana de Recerca i Estudis Avançats Barcelona 08010 Spain

Funding

Agència de Gestió d'Ajuts Universitaris i de Recerca · Xunta de Galicia · Agencia Estatal de Investigación

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