A Metal‐Organic Framework Incorporating Eight Different Size Rare‐Earth Metal Elements: Toward Multifunctionality À La Carte
Source abstract
Abstract
Abstract Multi‐metallic multivariate (MTV) rare earth (RE) metal−organic frameworks (MOFs) are of interest for the development of multifunctional materials, however examples with more than three RE cations are rare and obstructed by compositional segregation during synthesis. Herein, this work demonstrates the synthesis of a multi‐metallic MTV RE MOF incorporating two, four, six, or eight different RE ions with different sizes and in nearly equimolar amounts and no compositional segregation. The MOFs are formed by a combination of RE cations (La, Ce, Eu, Gd, Tb, Dy, Y, and Yb) and a 1,7‐di(4‐carboxyphenyl)‐1,7‐dicarba‐closo‐dodecaborane (mCB‐L) linker. The steric bulkiness and acidity of mCB‐L is crucial for the incorporation of different size RE ions into the MOF structure. Demonstration of the incorporation of all RE cations is performed via compositional and structural characterization. The more complex MTV MOF, including all eight RE ions (mCB‐8RE), are also characterized using optical, thermal, and magnetic techniques. Element‐selective X‐ray absorption spectroscopy and X‐ray Magnetic Circular Dichroism measurements allow us to characterize spectroscopically each of the eight RE ions and determine their magnetic moments. This work paves the way for the investigation of MTV MOFs with the possibility to combine RE ions à la carte for diverse applications.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Lanthanide and Transition Metal Complexes · Magnetism in coordination complexes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Inorganic Materials and Catalysis Laboratory (LMI) Institut de Ciència de Materials de Barcelona (ICMAB‐CSIC) Campus UAB Bellaterra 08193 Spain
Shandong Provincial Key Laboratory of Monocrystalline Silicon Semiconductor Materials and Technology College of Chemistry and Chemical Engineering Dezhou University Dezhou 253023 China
Department of Chemistry University of Southampton Highfield Southampton SO17 1BJ UK
Instituto de Nanociencia y Materiales de Aragón (INMA) Departamento de Física de la Materia Condensada CSIC‐Universidad de Zaragoza Zaragoza 50009 Spain
ALBA Synchrotron Light Source Cerdanyola del Vallès Barcelona 08290 Spain
Catalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and Barcelona Institute of Science and Technology (BIST) Bellaterra Barcelona 08193 Spain
Fronteras en Química de Materiales Materials Science Institute of Madrid‐Spanish National Research Council (ICMM‐CSIC) Madrid 28049 Spain
EUSS Research Group Escola Universitària Salesiana de Sarrià (EUSS) Passeig Sant Joan Bosco, 74 Barcelona 08017 Spain
Funding
Ministerio de Economía y Competitividad · Generalitat de Catalunya · China Scholarship Council
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