Aerogel Fibers Made via Generic Sol‐Gel Centrifugal Spinning Strategy Enable Dynamic Removal of Volatile Organic Compounds From High‐Flux Gas

Abstract Aerogels with ultrahigh porosity and large specific surface area have demonstrated great potential for capturing volatile organic compounds (VOCs). Especially, aerogel fiber aggregates with macropores formed by overlapping aerogel fibers and mesopores in the aerogel fibers might realize fast sorption kinetics and high sorption capacity simultaneously. However, how to develop fast fabrication and large‐scale production of aerogel fibers remains a challenge. Herein, a generic sol‐gel centrifugal spinning (SCS) strategy with a spinning rate capable of reaching 700 m min⁻¹ is developed for producing aerogel fibers. The representative SCS aerogel fiber made from aramid nanofiber (ANF) dispersion exhibits a large specific surface area (313 m² g⁻¹) and high tensile strength (12.48 MPa). The SCS strategy is further applied to fabricate various kinds of aerogel fibers, including sodium alginate, cellulose, and chitosan. The ANF aerogel fiber aggregates exhibit superior VOC adsorption capacity of 438.0 mg g⁻¹ under an ultrafast gas flux of 3.8 × 10⁴ L m⁻² h⁻¹, which also has satisfactory cyclic stability. This work not only develops a powerful and generic strategy for fabricating aerogel fibers in large scale, but also provides inspiration for applying these SCS aerogel fibers in dynamic removal of VOCs and other environmental protection fields.