Programmable Microfluidic‐Assisted Highly Conductive Hydrogel Patches for Customizable Soft Electronics

Abstract The utilization of hydrogels in soft electronics has led to significant progress in the field of wearable and implantable devices. However, challenges persist in hydrogel electronics, including the delicate equilibrium between stretchability and electrical conductivity, intricacies in miniaturization, and susceptibility to dehydration. Here, a lignin‐polyacrylamide (Ag‐LPA) hydrogel composite endowed with anti‐freeze, self‐adhesive, exceptional water retention properties, and high stretchability (1072%) is presented. Notably, this composite demonstrated impressive electrical conductivity at room temperature (47.924 S cm⁻¹) and extremely cold temperatures (42.507 S cm⁻¹). It is further proposed for microfluidic‐assisted hydrogel patches (MAHPs) to facilitate customizable designs of the Ag‐LPA hydrogel composite. This approach enhances water retention and offers versatility in packaging materials, making it a promising choice for enduring soft electronics applications. As a proof‐of‐concept, soft electronics across diverse applications and dimensions, encompassing healthcare monitoring, environmental temperature sensing, and 3D‐spring pressure monitoring electronics are successfully developed. The scenery of an extremely cold environment is further extended. The conductivity of the embedded Ag‐LPA hydrogel composite unveils the potential of MAHPs in polar rescue missions. It is envisioned that MAHPs will impact the development of sophisticated and tailored soft electronics, thereby forging new frontiers in engineering applications.