journal article·2009-03

Characterization of polymer electrolytes based on high molecular weight PVC and Li2SO4

S. Ramesh, K.Y. Ng

Current Applied Physics· Volume 9· Issue 2
Publisher page

Abstract

Abstract The polymer–salt complex with high molecular weight poly(vinyl chloride) (PVC) as the host polymer and lithium sulphate (Li2SO4) as the dopant salt are constructed in the form of thin film. Ionic conductivity studies in the temperature range of 303–373 K are performed for polymer complexes with 75% and 85% PVC. Arrhenius and Vogel–Tamman–Fulcher (VTF) behaviour was observed before and after the Tg of polymer, respectively. Dielectric constant and electrical modulus were analyzed and it was concluded that the films had ion conducting potential. Fourier transform infrared (FTIR) study confirmed that complexation occurred between PVC and Li2SO4.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Conducting polymers and applications · Ionic liquids properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (21)

Show source-provided references
1. Ramesh · Materials Science and Engineering B · 2001 · 85 · 1110.1016/S0921-5107(01)00555-4 ↗
2. Jacob · Solid State Ionics · 1997 · 98 · 16710.1016/S0167-2738(97)00117-3 ↗
3. Jiang · Electrochimica Acta · 1997 · 42 · 266710.1016/S0013-4686(97)00005-4 ↗
4. Huang · Solid State Ionics · 1996 · 85 · 7910.1016/0167-2738(96)00044-6 ↗
5. Vickraman · Materials Letters · 2006 · 60 · 343110.1016/j.matlet.2006.03.028 ↗
6. Odian · 1991
7. Ogihara · Electrochimica Acta · 2004 · 49 · 179710.1016/j.electacta.2003.12.011 ↗
8. Souquet · Solid State Ionics · 1994 · 70/71 · 33710.1016/0167-2738(94)90333-6 ↗
9. Rodrigues · Electrochimica Acta · 2007 · 53 · 142710.1016/j.electacta.2007.03.030 ↗
10. Bohnke · Solid State Ionics · 1993 · 66 · 10510.1016/0167-2738(93)90033-Y ↗
11. Cha · Electrochimica Acta · 2004 · 50 · 33510.1016/j.electacta.2004.01.101 ↗
12. Williams · Journal of the American Chemical Society · 1955 · 77 · 370110.1021/ja01619a008 ↗
13. Qian · Electrochimica Acta · 2001 · 46 · 182910.1016/S0013-4686(00)00723-4 ↗
14. Reicha · Journal of Physics D: Applied Physics · 1991 · 24 · 36910.1088/0022-3727/24/3/020 ↗
15. Almond · Solid State Ionics · 1983 · 11 · 5710.1016/0167-2738(83)90063-2 ↗
16. Khiar · Physica B: Condensed Matter · 2006 · 373 · 2310.1016/j.physb.2005.10.104 ↗
17. Mishra · Solid State Ionics · 1998 · 106 · 11310.1016/S0167-2738(97)00493-1 ↗
18. Chandra · Physica B: Condensed Matter · 2007 · 11810.1016/j.physb.2006.05.010 ↗
19. Ramesh · Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy · 2007 · 66 · 123710.1016/j.saa.2006.06.012 ↗
20. Uma · Materials Chemistry and Physics · 2005 · 90 · 23910.1016/j.matchemphys.2003.11.010 ↗
21. Uma · Materials Chemistry and Physics · 2004 · 85 · 13110.1016/j.matchemphys.2003.12.012 ↗