journal article·2026-03

Sulfur‐Doped Vanadium Oxide for High‐Performance and Stable Cathode Material of Zinc‐Ion Batteries

Kittima Lolupiman, Chengwu Yang, Pattaraporn Woottapanit, Wiwittawin Sukmas, Wanwisa Limphirat, Nadnudda Rodthongkum, Xinyu Zhang, Guanjie He, Jiaqian Qin

Advanced Functional Materials· Volume 36· Issue 18
Publisher page

Abstract

Abstract Vanadium oxides (V 2 O 5 ) are promising alternatives to the cathode for zinc‐ion batteries with multivalent electrons and layered structures that support reversible ion insertion‐extraction and provide higher theoretical capacity. However, they suffer from poor electronic conductivity, high material dissolution into electrolytes, and structural degradation, resulting in reduced capacity and shorter lifespans. Herein, the synthesized sulfur‐doped V 2 O 5 via a controlled calcination process to achieve high‐performance cathode materials. The optimized conditions lead to V 2 O 5 material with increased interlayer spacing, improved structural stability, and enhanced electronic conductivity. Sulfur doping introduces defect sites, which promotes faster Zn 2 ⁺ ion diffusion and improves charge transfer kinetics. These contribute to the excellent electrochemical performance of the S‐doped V 2 O 5 . As a result, it achieves a high specific capacity of 142.2 mAh g −1 and impressive long‐term stability over 5,000 cycles at a current density of 2 A g −1 . These findings suggest that S‐doped V 2 O 5 is a promising cathode material for high performance and stable zinc‐ion batteries and can be an alternative cathode material for next generation energy storage applications.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advanced battery technologies research · Advancements in Battery Materials · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

International Graduate Program of Nanoscience & Technology (Interdisciplinary) Graduate School Chulalongkorn University Bangkok 10330 Thailand

Department of Materials Science Faculty of Science Chulalongkorn University Bangkok 10330 Thailand

State Key Laboratory of Metastable Materials Science and Technology Yanshan University Qinhuangdao 066004 P. R. China

Extreme Condition Physics Research Laboratory and Center of Excellence in Physics of Energy Materials (CE:PEM) Department of Physics Faculty of Science Chulalongkorn University Bangkok 10330 Thailand

Synchrotron Light Research Institute (Public Organization) Nakhon Ratchasima 30000 Thailand

Department of Chemistry Faculty of Science Chulalongkorn University Bangkok 10330 Thailand

Center of Excellence in Responsive Wearable Materials Metallurgy and Materials Science Research Institute Chulalongkorn University Bangkok 10330 Thailand

Christopher Ingold Laboratory Department of Chemistry University College London London WC1H 0AJ UK

Funding

National Natural Science Foundation of China · National Research Council of Thailand

References (39)

Show source-provided references
1. 10.1016/j.est.2025.11583010.1016/j.est.2025.115830 ↗
2. 10.1016/j.epsr.2024.11096310.1016/j.epsr.2024.110963 ↗
3. 10.1016/j.est.2023.10808110.1016/j.est.2023.108081 ↗
4. 10.1021/acsaem.4c0201610.1021/acsaem.4c02016 ↗
5. 10.1021/acs.chemrev.9b0062810.1021/acs.chemrev.9b00628 ↗
6. 10.1016/j.nxener.2024.10011910.1016/j.nxener.2024.100119 ↗
7. 10.55713/jmmm.v34i3.208410.55713/jmmm.v34i3.2084 ↗
8. 10.1002/aesr.20230013910.1002/aesr.202300139 ↗
9. 10.1016/j.ensm.2022.02.03010.1016/j.ensm.2022.02.030 ↗
10. 10.1016/j.ensm.2024.10363510.1016/j.ensm.2024.103635 ↗
11. 10.3390/inorganics1103011810.3390/inorganics11030118 ↗
12. 10.1002/aenm.20200092710.1002/aenm.202000927 ↗
13. 10.1016/j.jelechem.2024.11857110.1016/j.jelechem.2024.118571 ↗
14. 10.1016/j.apsusc.2021.15091910.1016/j.apsusc.2021.150919 ↗
15. 10.1016/j.nanoen.2021.10587610.1016/j.nanoen.2021.105876 ↗
16. 10.1002/ange.20191220310.1002/ange.201912203 ↗
17. 10.1002/adfm.20180837510.1002/adfm.201808375 ↗
18. 10.1016/j.cej.2021.13376510.1016/j.cej.2021.133765 ↗
19. 10.1021/ja403232d10.1021/ja403232d ↗
20. 10.1016/j.jcis.2020.04.07210.1016/j.jcis.2020.04.072 ↗
21. 10.1002/celc.20230055010.1002/celc.202300550 ↗
22. 10.1186/s11671-015-1095-910.1186/s11671-015-1095-9 ↗
23. 10.1016/S0022-3093(02)00945-610.1016/S0022-3093(02)00945-6 ↗
24. 10.1007/s10854-023-11154-710.1007/s10854-023-11154-7 ↗
25. 10.2136/sssaj2019.01.000810.2136/sssaj2019.01.0008 ↗
26. 10.1002/smtd.20190067010.1002/smtd.201900670 ↗
27. 10.1002/cssc.20190101510.1002/cssc.201901015 ↗
28. 10.1016/j.nanoen.2021.10616410.1016/j.nanoen.2021.106164 ↗
29. 10.1016/j.egyr.2020.03.02910.1016/j.egyr.2020.03.029 ↗
30. 10.1039/C8CC02250J10.1039/C8CC02250J ↗
31. 10.1016/j.nanoen.2020.10451910.1016/j.nanoen.2020.104519 ↗
32. 10.1021/acsaem.3c0172410.1021/acsaem.3c01724 ↗
33. 10.1126/science.124962510.1126/science.1249625 ↗
34. Almodóvar P. · ElectroChem · 2020 · 7 · 2102
35. 10.1007/s10854-022-09531-910.1007/s10854-022-09531-9 ↗
36. 10.1002/admt.20210079910.1002/admt.202100799 ↗
37. 10.1002/batt.20210000610.1002/batt.202100006 ↗
38. 10.1021/acsnano.0c0466910.1021/acsnano.0c04669 ↗
39. 10.1103/PhysRevB.30.559610.1103/PhysRevB.30.5596 ↗