journal article·2024-02

Investigation of gradient band gap in Cu2ZnSnS4 thin films with residual strain

Sungwook Hong

Publisher page

Abstract

This study investigates the change in the band gap of Cu 2ZnSnS 4 (CZTS) thin films under a gradual change in the residual strain of the thin films. Two CZTS thin film samples are fabricated at different initial substrate temperatures before annealing. X-ray diffraction results are obtained at various incidence angles, and the residual strains at the incidence angles are obtained from the Williamson–Hall plot. The larger the mean residual strain of the CZTS thin films, the greater are the redshift and full width at half maximum of the main Raman peak position. Results of Tauc plot analysis show that the CZTS thin film samples exhibit a gradient band gap. The sample with a wider distribution of the residual strain shows a greater band gap variation.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (81)

Show source-provided references
1. Cu2ZnSnS4 thin film solar cells
2. Electrical and optical properties of stannite-type quaternary semiconductor thin films10.1143/JJAP.27.2094 ↗
3. Ab initio investigation of potential indium and gallium free chalcopyrite compounds for photovoltaic application10.1016/j.jpcs.2005.09.097 ↗
4. Characterization of vibrational and mechanical properties of quaternary compounds Cu2ZnSnS4 and Cu2ZnSnSe4 in kesterite and stannite structures10.1103/PhysRevB.84.205201 ↗
5. Detailed balance limit of efficiency of p‐n junction solar cells10.1063/1.1736034 ↗
6. Modeling of ZnO/MoS2/CZTS photovoltaic solar cell through window, buffer and absorber layers optimization10.1016/j.mseb.2020.114816 ↗
7. Enhancement in efficiency of CZTS solar cell by using CZTSe BSF layer10.1016/j.solener.2021.08.035 ↗
8. Cd-free Cu(in,Ga)(Se,S)2 thin-film solar cell with record efficiency of 23.3510.1109/JPHOTOV.2019.2937218 ↗
9. Solar cell efficiency tables (Version 61)10.1002/pip.3646 ↗
10. Cu2ZnSn S4 solar cells with over 10% power conversion efficiency enabled by heterojunction heat treatment10.1038/s41560-018-0206-0 ↗
11. Device characteristics of CZTSSe thin-film solar cells with 12.6% efficiency10.1002/aenm.201301465 ↗
12. Over 12% efficient kesterite solar cell via back interface engineering10.1016/j.jechem.2022.08.031 ↗
13. Kesterite Cu2ZnSnS4 as a low-cost inorganic hole-transporting material for high-efficiency perovskite solar cells10.1021/acsami.5b09572 ↗
14. Perovskite-kesterite monolithic tandem solar cells with high open-circuit voltage10.1063/1.4899275 ↗
15. Progress in CZTS as hole transport layer in perovskite solar cell10.1016/j.solener.2019.12.016 ↗
16. A novel and cost effective CZTS hole transport material applied in perovskite solar cells10.1039/C8CE01337C ↗
17. Efficiency enhancement of Cu2ZnSnS4 monograin layer solar cells via absorber post-growth treatments10.1016/j.solmat.2022.112090 ↗
18. Influence of solvent on solution processed Cu2ZnSnS4 nanocrystals and annealing induced changes in the optical, structural properties of CZTS film10.1016/j.cap.2020.05.003 ↗
19. Characteristics of Cu2ZnSn(S1-xSex)4 thin films crystallized with various sulfur and selenium vapor sources10.1080/15421406.2015.1076327 ↗
20. Characterization of thermally evaporated CZTSe thin films used by compositionally controlled alloys10.1016/j.optmat.2016.09.070 ↗
21. CZTSSe solar cell efficiency improvement using a new band-gap grading model in absorber layer10.1007/s00339-017-1371-x ↗
22. Energy band-gap shift with elastic strain in GaxIn1− xP epitaxial layers on (001) GaAs substrates10.1063/1.332252 ↗
23. Effects of Cu+ ion implantation on band gap and Raman shift of Cu2ZnSnS4 thin films10.1016/j.cap.2023.04.008 ↗
24. Band gap shift of Cu2ZnSnS4 thin film by residual stress10.1016/j.jallcom.2019.05.290 ↗
25. Multiple band gap semiconductor/electrolyte solar energy conversion10.1021/jp010552j ↗
26. Two-terminal III–V//Si triple-junction solar cell with power conversion efficiency of 35.9% at AM1.5g10.1002/pip.3503 ↗
27. Silver-assisted optimization of band gap gradient structure of Cu(In,Ga)Se2 solar cells via SCAPS10.1016/j.solener.2021.09.011 ↗
28. Gradient band gap perovskite films with multiple photoluminescence peaks10.1016/j.optmat.2019.109513 ↗
29. Gradient band gap CZTSSe prepared via sputtering from quaternary ceramic targets followed with annealing under different atmospheres10.1016/j.solener.2023.05.038 ↗
30. Properties of Cu2ZnSnS4 films with respect to sulfurization time investigated using Cu-Zn-Sn films deposited by Co-sputtering10.1080/15421406.2015.1076323 ↗
31. Characteristics of Cu2ZnSnS4 film formed by using Co-sputtered precursors and selenization10.1080/15421406.2012.693319 ↗
32. Effect of precursors pre-annealing on the microstructure of Cu2ZnSnS4 thin films on titanium foil substrate10.1016/j.tsf.2018.08.035 ↗
33. Glancing-incidence X-ray diffraction for depth profiling of polycrystalline layers10.1107/S0021889805042779 ↗
34. Depth profile of the lattice constant of the Cu-poor surface layer in (Cu2Se)1−x(In2Se3)x evidenced by grazing incidence X-ray diffraction10.1016/S0022-3697(03)00074-X ↗
35. X-ray line broadening from filed aluminium and wolfram10.1016/0001-6160(53)90006-6 ↗
36. Characterization of thin films by low incidence X-ray diffraction
37. Compositional depth profiling of polycrystalline thin films by grazing-incidence X-ray diffraction10.1107/S002188980601987X ↗
38. Cullity · 2014
39. Effect of Ce doping on crystallite size, band gap, dielectric and antibacterial properties of photocatalyst copper oxide Nano-structured thin films
40. Estimation of crystallite size, lattice strain and dislocation density of nanocrystalline carbonate substituted hydroxyapatite by X-ray peak variance analysis10.1016/j.mspro.2014.07.260 ↗
41. Anomalous x-ray diffraction peak broadening and lattice strains in Zn1− xCoxO dilute magnetic semiconductors10.1088/0953-8984/21/7/075801 ↗
42. Structural, optical and electrical properties of spray-deposited CZTS thin films under a non-eqilibrium growth condition10.1088/0022-3727/45/44/445103 ↗
43. Observation of high nonlinearity in Bi doped BixIn35-xSe65 thin films with annealing10.1038/s41598-021-01134-4 ↗
44. Tuning in linear and nonlinear optical parameters by interfacial mixing of Sb/Ag2Se bilayer thin films under annealing at different temperatures for optoelectronic applications
45. Wilson · 1949 · 5
46. The diffraction of X rays by distorted crystal aggregates-1
47. Hammond · 2015 · 263
48. The effect of dislocation contrast on x-ray line broadening: a new approach to line profile analysis10.1063/1.117951 ↗
49. Interfaces and stresses in thin films10.1016/S1359-6454(99)00286-4 ↗
50. Intrinsic stress response of low and high mobility solute additions to Cu thin films10.1063/1.5008269 ↗
51. Surface stress model for intrinsic stresses in thin films10.1557/JMR.2000.0354 ↗
52. Residual stresses in deposited thin-film material layers for micro-and nano-systems manufacturing10.3390/mi13122084 ↗
53. Stress in thin films and coatings: current status, challenges, and prospects10.1116/1.5011790 ↗
54. Correlation between crystallite size–optical gap energy and precursor molarities of ZnO thin films10.1088/1674-4926/35/4/042001 ↗
55. Characterization of CdTe thin film—dependence of structural and optical properties on temperature and thickness10.1016/j.solmat.2004.01.017 ↗
56. Crystallite size dependence of band gap energy for electrodeposited ZnO grown at different temperatures10.1016/j.solmat.2006.03.008 ↗
57. Growth of silver nanoparticles within the tellurovanadate amorphous matrix: optical band gap and band tailing properties, beside the Williamson-Hall estimation of crystallite size and lattice strain10.1016/j.ceramint.2019.01.094 ↗
58. Structural, morphological, and linear/non-linear optical properties tuning in Ag60-xSe40Tex films by thermal annealing for optoelectronics10.1016/j.jnoncrysol.2022.121742 ↗
59. Comprative study of crystallite size using Williamson-Hall and Debye-Scherrer plots for ZnO nanoparticles10.1088/2043-6254/ab52f7 ↗
60. Strain-induced indirect to direct bandgap transition in multilayer WSe210.1021/nl501638a ↗
61. Study of the Raman peak shift and the linewidth of light‐emitting porous silicon10.1063/1.355808 ↗
62. Residual stresses and Raman shift relation in anatase TiO2 thin film10.1016/j.tsf.2009.02.141 ↗
63. An application of Raman spectroscopy on the measurement of residual stress in porous silicon10.1016/j.optlaseng.2004.09.005 ↗
64. Study of polycrystalline Cu2ZnSnS4 films by Raman scattering10.1016/j.jallcom.2011.04.097 ↗
65. Calculation of the lattice dynamics and Raman spectra of copper zinc tin chalcogenides and comparison to experiments
66. Cu2ZnSnS4 absorption layers with controlled phase purity10.1038/srep09291 ↗
67. Residual stress dependent anisotropic band gap of various (hkl) oriented Bai2 films10.1063/1.4832437 ↗
68. Stress-induced shift of band gap in ZnO nanowires from finite-element modeling10.1103/PhysRevApplied.8.034031 ↗
69. Optical properties and electronic structure of amorphous germanium10.1002/pssb.19660150224 ↗
70. Schroder · 2006 · 563
71. Electrosynthesis and characterization of CdSe thin films: optimization of preparative parameters by photoelectrochemical technique10.1016/j.jpcs.2006.06.015 ↗
72. Compositional dependence optical properties study of As40Se60–xSbx thin films10.1016/j.tsf.2011.10.029 ↗
73. Laser induced Bi diffusion in As40S60 thin films and optical properties change probed by FTIR and XPS10.1016/j.optmat.2016.10.004 ↗
74. Tauc · 1974 · 159
75. Determination of band gap energy (Eg) of Cu2ZnSnSe4 thin films: on the discrepancies of reported band gap values10.1063/1.3457172 ↗
76. Shallow defects in Cu2ZnSnS410.1016/j.physb.2009.08.206 ↗
77. Improved crystallinity, optical and electrical properties of ZnSe–Se2O5 films through O+ implantation10.1016/j.vacuum.2022.111215 ↗
78. Tailoring the structural and optical characteristics of InGaN/GaN multilayer thin films by 12MeV Si ions irradiations10.1016/j.mssp.2017.03.004 ↗
79. Effect of deposition temperature on the properties of Cu2ZnSnS4 (CZTS) thin films10.1016/j.spmi.2017.02.003 ↗
80. Fabrication of Cu2ZnSnS4 (CZTS) absorber films based on different compound targets10.1016/j.jallcom.2016.08.053 ↗
81. The band gap of Cu2ZnSnSe4: effect of order-disorder10.1063/1.4896315 ↗