Ultrathin Composite Li Electrode for High‐Performance Li Metal Batteries: A Review from Synthetic Chemistry
Source abstract
Abstract
Abstract Li metal anode attracts tremendous attention in next‐generation battery systems with high energy density, but volume change and dendritic growth limit its practical applications. Composite Li electrode can fundamentally suppress the volume effect and decrease the local current density, ensuring long‐term cycling life. However, up to now, there is only limited success in preparing multifarious composite Li electrode, especially in thickness, posing great obstacles to further promoting its research and application. In this review, the thickness of composite Li electrode are strategically focussed upon and the merits and existing challenges of ultrathin composite Li electrode are evaluated. Meanwhile, the design principles and fundamental requirements for ultrathin composite Li electrode in the future are summarized and the existing cases related to this field are outlined as much as possible from synthetic chemistry, hoping it can serve as a handbook to provide a comprehensive understanding and guide reliable fabrication of advanced composite Li electrode. Challenges and opportunities regarding this burgeoning field are also critically evaluated at the end of this review.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced battery technologies research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
College of Materials Science and Engineering Taiyuan University of Technology Taiyuan Shanxi 030024 China
College of Chemistry and Molecular Engineering Peking University Beijing 100871 China
Key Laboratory of Advanced Materials Technologies International (HongKong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies College of Materials Science and Engineering Fuzhou University Fuzhou Fujian 350108 China
State Key Lab of Chemical Resource Engineering College of Science and College of Energy Beijing University of Chemical Technology Beijing 100092 China
State Key Laboratory of Organic Electronics and Information Displays (SKLOEID) Institute of Advanced Materials (IAM) Nanjing University of Posts and Telecommunications Nanjing 210023 China
Corrosion and Protection Engineering Technology Research Center of Shanxi Province Taiyuan Shanxi 030024 China
Funding
Natural Science Foundation of Shanxi Province · National Key Research and Development Program of China · Natural Science Foundation of Fujian Province · National Natural Science Foundation of China
References (100+)
Show source-provided references
1. 10.1038/nature1147510.1038/nature11475 ↗
2. 10.1016/j.ensm.2019.03.00210.1016/j.ensm.2019.03.002 ↗
3. Li S. Q. · Materials · 2020 · 13, 844
4. 10.1016/j.enconman.2014.05.00310.1016/j.enconman.2014.05.003 ↗
5. 10.1039/C8CS00237A10.1039/C8CS00237A ↗
6. 10.1002/aenm.20160170910.1002/aenm.201601709 ↗
7. 10.1016/j.nanoen.2020.10551610.1016/j.nanoen.2020.105516 ↗
8. 10.1016/j.ensm.2018.04.03010.1016/j.ensm.2018.04.030 ↗
9. 10.1038/s41578-019-0142-z10.1038/s41578-019-0142-z ↗
10. 10.1002/aenm.20190378010.1002/aenm.201903780 ↗
11. 10.1002/smtd.20210087710.1002/smtd.202100877 ↗
12. 10.1002/smll.20170341910.1002/smll.201703419 ↗
13. 10.1016/j.mtnano.2019.10005710.1016/j.mtnano.2019.100057 ↗
14. 10.3390/app1009309810.3390/app10093098 ↗
15. 10.1016/j.pecs.2015.01.00210.1016/j.pecs.2015.01.002 ↗
16. Demirocak D. E. · Appl. Sci.‐Basel · 2017 · 7 · 7
17. 10.1002/ese3.9510.1002/ese3.95 ↗
18. 10.1002/er.376210.1002/er.3762 ↗
19. 10.1016/j.energy.2021.12288110.1016/j.energy.2021.122881 ↗
20. 10.3390/en1206107410.3390/en12061074 ↗
21. 10.1088/1674-1056/ab5d0710.1088/1674-1056/ab5d07 ↗
22. 10.3389/fchem.2020.0040910.3389/fchem.2020.00409 ↗
23. 10.1007/s12598-018-1049-310.1007/s12598-018-1049-3 ↗
24. 10.1002/adfm.20210792310.1002/adfm.202107923 ↗
25. 10.1002/adma.20190324810.1002/adma.201903248 ↗
26. 10.1016/j.jechem.2019.12.02410.1016/j.jechem.2019.12.024 ↗
27. 10.1002/adma.20170116910.1002/adma.201701169 ↗
28. 10.1002/advs.20210391010.1002/advs.202103910 ↗
29. 10.1002/aenm.20140227310.1002/aenm.201402273 ↗
30. 10.1016/j.ensm.2017.12.00210.1016/j.ensm.2017.12.002 ↗
31. 10.1016/j.coelec.2019.05.00110.1016/j.coelec.2019.05.001 ↗
32. 10.1007/s10853-018-3093-710.1007/s10853-018-3093-7 ↗
33. 10.1039/c3cp54165g10.1039/c3cp54165g ↗
34. 10.1039/c3cs60177c10.1039/c3cs60177c ↗
35. 10.1007/s10800-013-0620-810.1007/s10800-013-0620-8 ↗
36. Suryatna A. · J. Chem.‐Ny · 2022 · 2022
37. 10.1039/D0CC03032E10.1039/D0CC03032E ↗
38. 10.1007/s11426-019-9519-910.1007/s11426-019-9519-9 ↗
39. 10.1002/advs.20200221210.1002/advs.202002212 ↗
40. 10.1002/anie.20191270110.1002/anie.201912701 ↗
41. 10.1002/chem.20190463110.1002/chem.201904631 ↗
42. 10.1016/S1872-5805(21)60081-110.1016/S1872-5805(21)60081-1 ↗
43. 10.1016/j.ensm.2018.03.02410.1016/j.ensm.2018.03.024 ↗
44. 10.1002/aenm.20200125710.1002/aenm.202001257 ↗
45. 10.1002/aenm.20160081110.1002/aenm.201600811 ↗
46. 10.1016/j.ensm.2022.12.04310.1016/j.ensm.2022.12.043 ↗
47. 10.1002/advs.20220523310.1002/advs.202205233 ↗
48. 10.1016/j.electacta.2018.05.10210.1016/j.electacta.2018.05.102 ↗
49. 10.1021/acsnano.5b0216610.1021/acsnano.5b02166 ↗
50. 10.1021/acs.chemmater.7b0149610.1021/acs.chemmater.7b01496 ↗
51. 10.1007/s41918-019-00054-210.1007/s41918-019-00054-2 ↗
52. 10.1002/smtd.20170041710.1002/smtd.201700417 ↗
53. 10.1021/acsenergylett.9b0053910.1021/acsenergylett.9b00539 ↗
54. 10.1021/acs.nanolett.0c0454610.1021/acs.nanolett.0c04546 ↗
55. 10.1002/cey2.14710.1002/cey2.147 ↗
56. 10.1016/j.jechem.2018.11.01610.1016/j.jechem.2018.11.016 ↗
57. 10.1002/smll.20220291110.1002/smll.202202911 ↗
58. Yue X. Y. · Prog. Chem. · 2022 · 34 · 683
59. 10.1021/acsami.7b1466210.1021/acsami.7b14662 ↗
60. 10.1021/acsaem.9b0092910.1021/acsaem.9b00929 ↗
61. 10.1039/D0QM01134G10.1039/D0QM01134G ↗
62. 10.1002/eem2.1210910.1002/eem2.12109 ↗
63. 10.1016/j.nanoen.2020.10472510.1016/j.nanoen.2020.104725 ↗
64. 10.1002/anie.20180703410.1002/anie.201807034 ↗
65. 10.1038/s41467-020-19246-210.1038/s41467-020-19246-2 ↗
66. 10.1002/anie.20190525110.1002/anie.201905251 ↗
67. 10.1002/ente.20200070010.1002/ente.202000700 ↗
68. 10.3389/fchem.2019.0072110.3389/fchem.2019.00721 ↗
69. 10.1002/adma.20190849410.1002/adma.201908494 ↗
70. 10.1038/s41560-021-00833-610.1038/s41560-021-00833-6 ↗
71. 10.1021/acs.nanolett.8b0410610.1021/acs.nanolett.8b04106 ↗
72. 10.1002/smtd.20180003510.1002/smtd.201800035 ↗
73. 10.1016/j.joule.2018.02.00110.1016/j.joule.2018.02.001 ↗
74. 10.1002/adfm.20160642210.1002/adfm.201606422 ↗
75. 10.1016/j.ensm.2018.07.01010.1016/j.ensm.2018.07.010 ↗
76. 10.1016/j.mtener.2021.10087110.1016/j.mtener.2021.100871 ↗
77. 10.1002/adfm.20180302310.1002/adfm.201803023 ↗
78. 10.1039/D2CC00123C10.1039/D2CC00123C ↗
79. 10.1016/j.nanoen.2020.10473110.1016/j.nanoen.2020.104731 ↗
80. 10.1016/j.cej.2022.13464310.1016/j.cej.2022.134643 ↗
81. 10.1021/acsnano.9b1008310.1021/acsnano.9b10083 ↗
82. 10.1016/j.ensm.2018.05.01710.1016/j.ensm.2018.05.017 ↗
83. 10.1016/j.ensm.2020.04.02210.1016/j.ensm.2020.04.022 ↗
84. 10.1016/j.jallcom.2019.15275310.1016/j.jallcom.2019.152753 ↗
85. 10.1007/s40843-021-1728-210.1007/s40843-021-1728-2 ↗
86. 10.1021/acsami.9b2253010.1021/acsami.9b22530 ↗
87. 10.1016/j.cclet.2021.10.05110.1016/j.cclet.2021.10.051 ↗
88. 10.1016/j.jmat.2019.02.00810.1016/j.jmat.2019.02.008 ↗
89. 10.1002/cey2.9510.1002/cey2.95 ↗
90. Qiu X. G. · Acta Phys.‐Chim. Sin. · 2021 · 37
91. 10.1002/advs.20210521310.1002/advs.202105213 ↗
92. 10.1149/1945-7111/ac316110.1149/1945-7111/ac3161 ↗
93. 10.1016/j.cej.2021.13439210.1016/j.cej.2021.134392 ↗
94. Wu L. L. · Inorg. Chem. · 2021 · 37 · 709
95. 10.1016/j.elecom.2019.10653510.1016/j.elecom.2019.106535 ↗
96. 10.1016/j.ensm.2018.05.00510.1016/j.ensm.2018.05.005 ↗
97. 10.1007/s12221-022-4953-y10.1007/s12221-022-4953-y ↗
98. 10.1039/C7TA08531A10.1039/C7TA08531A ↗
99. 10.1002/anie.20170209910.1002/anie.201702099 ↗
100. 10.1039/C8CC04422H10.1039/C8CC04422H ↗