O‐Tailored Microstructure‐Engineered Interface toward Advanced Room Temperature All‐Solid‐State Na Batteries
Source abstract
Abstract
Abstract The severe parasitic interface reaction and dendrite growth retard the practical applications of all‐solid‐state (ASS) Na batteries with sulfide solid electrolytes (SEs). Here, a novel composite SE is proposed, with a high ionic conductivity, composed of Na3SbS4 (NSS) and oxysulfide glass. The study reveals that the P2S7‐aOa and PS4‐aOa units in oxysulfide play various roles: The former is deoxidized to release free O ions, which reacts with the anode via migrating to form oxides, favoring an improved interface stability. The latter is highly stable upon cycling, thereby maintaining an ion transport network. Meanwhile, NSS acts as a dendrite predator via reacting with penetrated Na. These advantages enable the resulting ASS Na battery with superior long‐term cycling performance at a high current density at room temperature, one of the best results so far. This discovery sheds light on innovative advanced SE materials through an oxysulfide‐based composite design.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Thermal Expansion and Ionic Conductivity
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Clean Nano Energy Center State Key Laboratory of Metastable Materials Science and Technology Yanshan University Qinhuangdao Hebei 066004 China
Institute of Solid State Physics Vienna University of Technology 1040 Vienna Austria
Yangtze Delta Region Institute (Huzhou) University of Electronic Science and Technology of China Huzhou 313002 China
Funding
National Natural Science Foundation of China
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