DataVXAdvanced Functional MaterialsPaper
journal article·2021-07

Near‐Linear Controllable Synthesis of Mesoporosity in Hierarchical UiO‐66 by Template‐Free Nucleation‐Competition

Jia‐Xin Li, Gang‐Gang Chang, Ge Tian, Chun Pu, Ke‐Xin Huang, Shan‐Chao Ke, Christoph Janiak, Xiao‐Yu Yang

Advanced Functional Materials· Volume 31· Issue 30
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Source abstract

Abstract

Abstract Hierarchies design of porosity in metal‐organic frameworks (MOFs) has gained significant interest in recent years, and customization of mesoporous sizes in MOFs is still quite challenging. Herein, a template‐free method by nucleation‐competition has been developed to realize a near‐linear control of the mesopore sizes (3–13 nm) in the hierarchical MOF UiO‐66(Hf). High selectivity of enzyme adsorption, high activity of bulky‐molecular catalysis, high stability of mesostructure, and extension to other MOFs further prove the success in the potential customization synthesis and applications.
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Research context

Catalysis & surfaces

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Mesoporous Materials and Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & School of Chemistry Chemical Engineering and Life Science & School of Materials Science and Engineering & International School of Materials Science and Engineering Wuhan University of Technology 122, Luoshi Road Wuhan Hubei 430070 China

Institut für Anorganische Chemie und Strukturchemie Heinrich‐Heine‐Universität Düsseldorf 40204 Düsseldorf Germany

School of Engineering and Applied Sciences Harvard University Cambridge MA 02138 USA

Funding

National Natural Science Foundation of China · Deutsche Forschungsgemeinschaft

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