Near‐Infrared Optical Synapses Based on Multilayer MoSe₂ Moiré Superlattice for Artificial Retina

Abstract Near‐infrared (NIR) synaptic devices have attracted great attention in the field of NIR vision sensors due to their highly parallel sensing and memory functions, which emulate the basic biomimetic behaviors of the human visual system. However, it is a great challenge for the 2D material to achieve NIR light response and integration, which obstructs the progress of NIR synaptic devices. Hence, a two‐terminal NIR synaptic device based on a multilayer MoSe₂ moiré superlattice is reported. The moiré structure dominated by interlayer excitons significantly enhances the interlayer coupling of multilayer MoSe₂, resulting in a narrower band gap nearly to that of bulk to achieve NIR light response and broadband absorption from 240 nm to 1700 nm. The existence of Se vacancies in MoSe₂ moiré superlattice makes the device show the fundamental synaptic performance. Furthermore, a 10×10 integrated retinal morphologic device array is constructed. Under the 100 s light pulse stimulation of 1060 nm, the pattern obtained after attenuation of 50 s still has a memory level of 14.84%, reflecting the excellent storage function under NIR illumination. This research opens up a new avenue for the realization of NIR artificial retina and bionic eye based on 2D materials.