1T’ Re_xMo_1−xS₂–2H MoS₂ Lateral Heterojunction for Enhanced Hydrogen Evolution Reaction Performance

Abstract The imperfect interfaces between 2D transition metal dichalcogenides (TMDs) are suitable for boosting the hydrogen evolution reaction (HER) during water electrolysis. Here, the improved catalytic activity at the spatial heterojunction between 1T’ Re_xMo_1−xS₂ and 2H MoS₂ is reported. Atomic‐scale electron microscopy confirms that the heterojunction is constructed by an in‐situ two‐step growth process through chemical vapor deposition. Electrochemical microcell measurements demonstrate that the 1T’ Re_xMo_1−xS₂–2H MoS₂ lateral heterojunction exhibits the best HER catalytic performance among all TMD catalysts with an overpotential of ≈84 mV at 10 mA cm⁻² current density and 58 mV dec⁻¹ Tafel slope. Kelvin probe force microscopy shows ≈40 meV as the work function difference between 2H MoS₂ and 1T’ Re_xMo_1−xS₂, facilitating the electron transfer from 2H MoS₂ to 1T’ Re_xMo_1−xS₂ at the heterojunction. First‐principles calculations reveal that Mo‐rich heterojunctions with high structural stability are formed, and the HER performance is improved with the combination of increased density of states near the Fermi level and optimal ΔG_H* as low as 0.07 eV. Those synergetic effects with many electrons and active sites with optimal ΔG_H* improve HER performance at the heterojunction. These results provide new insights into understanding the role of the heterojunction for HER.