journal article·2025-06-23Open access

Development of Young’s Modulus of Illite/Smectite—CaCO3 Composites After Various Firing Temperatures

Štefan Csáki, Tibor Kovács, Martin Keppert, Vojtěch Pommer, František Lukáč, Michal Knapek, Peter Minárik, Anton Trník

Crystals· Volume 15· Issue 7

Abstract

Illitic clays are one of the most important materials used in the ceramic industry. Carbonates support the densification and the sintering of ceramics. Five mixtures of illitic clay with calcite were prepared aiming for the crystallization of anorthite ceramics. The stoichiometric ratio of anorthite crystallization was determined at 21.6 wt.% of calcite content. To reveal the effect of calcite on the crystallization processes, two more mixtures were prepared below the stoichiometric composition (17.6 wt.% and 19.6 wt.%) and two more mixtures above the ideal composition (23.6 wt.% and 25.6 wt.%). X-ray diffraction revealed that gehlenite and Ca-feldspar were formed, which are the intermediate phases in anorthite crystallization. However, due to the low purity of illitic clay and the low firing temperature, no anorthite formation was observed. The influence of calcite content on Young’s modulus was negligible. However, a clear effect on the open porosity was revealed.
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Research context

OpenAlex topics: Building materials and conservation · Cultural Heritage Materials Analysis · Clay minerals and soil interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Physics, Faculty of Natural Sciences and Informatics, Constantine the Philosopher University in Nitra, Tr. A. Hlinku 1, 949 01 Nitra, Slovakia

Department of Horticultural Machinery, Faculty of Horticulture, Mendel University in Brno, Valtická 337, 691 44 Lednice, Czech Republic

Department of Materials Engineering and Chemistry, Faculty of Civil Engineering, Czech Technical University in Prague, Thákurova 7, 166 29 Prague, Czech Republic

Institute of Plasma Physics, The Czech Academy of Sciences, Za Slovankou 3, Prague 8, 182 00 Prague, Czech Republic

Department of Physics of Materials, Faculty of Mathematics and Physics, Charles University, Ke Karlovu 5, 121 16 Prague, Czech Republic

Funding

Constantine the Philosopher University

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