Synthesis and Crystal Structure of Dimethyl{N-[(2-oxy-1-naphthyl)methylene]leucinato}silicon
Source abstract
Abstract
The title compound was prepared by reaction of the Schiff base ligand N-(2-hydroxy-1-naphthylidene)leucine with dichlorodimethylsilane in the presence of triethylamine as base. The resulting pentacoordinate silicon complex was characterized by NMR, IR, UV-Vis spectroscopy and melting point. The structure was confirmed by single-crystal X-ray diffraction data. It crystallizes in the monoclinic space group Ic with unit cell dimensions a = 7.2030(6), b = 22.9842(14), c = 10.8946(12) Å, β = 96.141(7)°, V = 1793.3(3) Å3, Z = 4.
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Research context
OpenAlex topics: Metal complexes synthesis and properties · Porphyrin and Phthalocyanine Chemistry · Magnetism in coordination complexes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, 09599 Freiberg, Germany
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