journal article·2025-06-19Open access

Structural, Thermophysical, and Radiation Shielding Properties of Lead–Bismuth Eutectic (LBE) Synthesized by Induction Melting

Radu Cristian Gavrea, Emanoil Surducan, Răzvan Hirian, Mioara Zagrai, Vasile Rednic

Crystals· Volume 15· Issue 6

Abstract

Lead–bismuth eutectic alloy (LBE, Pb44.5Bi55.5) has emerged as a promising candidate for use in advanced nuclear and solar energy systems due to its favorable thermophysical characteristics and radiation shielding capabilities. The aim of this research is to assess the applicability of the induction melting technique to synthesize LBE. This paper presents a comprehensive evaluation of the structural, thermophysical, and radiation shielding properties of the obtained LBE sample. Various techniques were employed to investigate the solid-to-liquid eutectic transformation, phase composition, morphology, and homogeneity of the obtained material. Experimental and theoretical determinations on density, void, molar volume, thermal conductivity, heat capacity, thermal diffusivity, and electrical conductivity were performed. Radiation shielding performance over photon energies ranging from 0.015 to 15 MeV was simulated using the Phy-X/PSD program. The results revealed the eutectic structure comprising Pb7Bi3 and Bi phases with near-ideal stoichiometry and a melting point of 127.6 °C. The alloy demonstrated a small void that corresponds to a high degree of sample compaction, high specific heat capacity, moderate thermal conductivity, low thermal diffusivity, and effective radiation shielding. These findings confirm that LBE obtained by the induction melting technique possesses the necessary structural stability and functional properties for integration into nuclear reactor and solar thermal technologies.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Radiation Shielding Materials Analysis · Nuclear materials and radiation effects · Thermodynamic and Structural Properties of Metals and Alloys

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Materials, Energy and Advanced Technologies Department, National Institute for Research and Development of Isotopic and Molecular Technologies, 67-103 Donat, 400293 Cluj-Napoca, Romania

Faculty of Physics, Babeş-Bolyai University Cluj-Napoca, 1 Kogălniceanu, 400084 Cluj-Napoca, Romania

Funding

Ministry of Education and Scientific Research

References (39)

Show source-provided references
1. Wang, W., Yang, C., You, Y., and Yin, H. (2023). A Review of Corrosion Behavior of Structural Steel in Liquid Lead–Bismuth Eutectic. Crystals, 13.10.3390/cryst13060968 ↗
2. Study of the physical and nuclear properties of liquid PbBiCd alloy coolant in nuclear fast reactor10.1016/j.jnucmat.2019.05.006 ↗
3. Environmental degradation of structural materials in liquid lead and lead-bismuth eutectic-cooled reactors10.1016/j.pmatsci.2022.100920 ↗
4. Corrosion behavior of T91 steel in liquid lead-bismuth eutectic at 550 °C: Effects of exposure time and dissolved oxygen concentration10.1016/j.corsci.2022.110405 ↗
5. Electrical properties of thermal oxide scales on pure iron in liquid lead–bismuth eutectic10.1016/j.corsci.2020.109052 ↗
6. Determination of 21 Po generation from lead–bismuth eutectic irradiated with neutrons10.1007/s10967-023-08839-y ↗
7. Montanari, R., Varone, A., Gregoratti, L., Kaciulis, S., and Mezzi, A. (2019). Lead-Bismuth Eutectic: Atomic and Micro-Scale Melt Evolution. Materials, 12.10.3390/ma12193158 ↗
8. A brief review of liquid heat transfer materials used in concentrated solar power systems and thermal energy storage devices of concentrated solar power systems10.1002/eng2.12576 ↗
9. Wang, G., and Wang, T. (2022). Effect Evaluation of Filling Medium Parameters on Operating and Mechanical Performances of Liquid Heavy Metal Heat Storage Tank. Sustainability, 14.10.3390/su142114551 ↗
10. A study of the effects of minor additives to Pb-Bi eutectic: Designing novel Pb-Bi-X liquid alloys for heat transfer applications10.1016/j.matdes.2018.08.044 ↗
11. Performance and parameter sensitivity comparison of CSP power cycles under wide solar energy temperature ranges and multiple working conditions10.1016/j.enconman.2020.112996 ↗
12. A review on the application of liquid metals as heat transfer fluid in Concentrated Solar Power technologies10.1016/j.ijhydene.2016.01.030 ↗
13. Review of the molten salt technology and assessment of its potential to achieve an energy efficient heat management in a decarbonized chemical industry10.1016/j.cej.2024.155819 ↗
14. Caraballo, A., Galán-Casado, S., Caballero, Á., and Serena, S. (2021). Molten salts for sensible thermal energy storage: A review and an energy performance analysis. Energies, 14.10.3390/en14041197 ↗
15. An overview of thermal energy storage systems10.1016/j.energy.2017.12.037 ↗
16. Heat transfer fluids for concentrating solar power systems—A review10.1016/j.apenergy.2015.01.125 ↗
17. Assessment of liquid metal technology status and research paths for their use as efficient heat transfer fluids in solar central receiver systems10.1016/j.solener.2013.03.025 ↗
18. Liquid metals for solar power systems10.1088/1757-899X/228/1/012012 ↗
19. The thermophysical properties of Bi-Ga alloys10.1016/j.molliq.2022.119912 ↗
20. Novakovic, R., Giuranno, D., Lee, J., Mohr, M., Delsante, S., Borzone, G., Miani, F., and Fecht, H.-J. (2022). Thermophysical Properties of Fe-Si and Cu-Pb Melts and Their Effects on Solidification Related Processes. Metals, 12.10.20944/preprints202201.0391.v1 ↗
21. Study of structural, physical, characteristics and radiation shielding parameters of Bi50-Pb40-Sn10 and Bi40-Pb40-Sn10-Cd10 alloys used for radiation therapy10.1080/10420150.2022.2063125 ↗
22. Herreros, A.F. (2024). Overview and History of Lead and Lead-Bismuth Fast Reactors (LFRs), Stanford University.
23. Grauer, M., Benndorf, C., Rohr, V., Paulmann, C., and Oeckler, O. (2024). Investigations of Some Disordered Quaternary Compounds in the Systems Ag/Pb/Sb/Se and Ag/Pb/Sb/Te. Crystals, 14.10.3390/cryst14090789 ↗
24. Thermal conductivity of lead and bismuth-lead eutectic melts up to 1300 K10.1016/j.nucengdes.2024.113166 ↗
25. Concetta, F., Sobolev, V.P., Aerts, A., Gavrilov, S., Lambrinou, K., Schuurmans, P., Gessi, A., Agostini, P., Ciampichetti, A., and Martinelli, L. (2015). Handbook on Lead-Bismuth Eutectic Alloy and Lead Properties, Materials Compatibility, Thermal-Hydraulics and Technologies, OECD/NEA.
26. Wei, Y., La, P., Zheng, Y., Zhan, F., Yu, H., Yang, P., Zhu, M., Bai, Z., and Gao, Y. (2025). Review of Molten Salt Corrosion in Stainless Steels and Superalloys. Crystals, 15.10.3390/cryst15030237 ↗
27. Molten salts: Potential candidates for thermal energy10.1002/er.8441 ↗
28. Jo, S., Kim, S., and Cho, J. (2024). A Fast Variance Reduction Technique for Efficient Radiation Shielding Calculations in Nuclear Reactors. Energies, 17.10.3390/en17225695 ↗
29. Xing, M., Fan, J., Shen, F., Lu, D., Li, L., Yu, H., and Fan, J. (2025). Comparative Analysis on the Characteristics of Liquid Lead and Lead–Bismuth Eutectic as Coolants for Fast Reactors. Energies, 18.10.3390/en18030596 ↗
30. POWDER CELL—A programfor the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns10.1107/S0021889895014920 ↗
31. Crystal data for Pb7Bi3, a superconducting ε-phase in the Pb-Bi system10.1017/S0885715600012185 ↗
32. Wyckoff, R.W.G. (1963). Crystal Structures, Interscience Publishers.
33. Review on thermal energy storage with phase change materials and applications10.1016/j.rser.2007.10.005 ↗
34. Thermophysical Properties of Lead-Bismuth Eutectic Alloyin Reactor Safety Analyses10.1080/18811248.2006.9711131 ↗
35. Thermal shock protection with scalable heat-absorbing aerogels10.1038/s41467-024-51530-3 ↗
36. Phy-X/PSD: Development of a user friendly online software for calculation of parameters relevant to radiation shielding and dosimetry10.1016/j.radphyschem.2019.108496 ↗
37. Evolution of the Radiation Shielding, Optical, and Luminescence Properties of PbO2-SiO2 Glass Systems and the Influence of Rare Earth Elements (Eu, Ce, Yb)10.3390/app15020864 ↗
38. Yin, S., Wang, H., Wang, S., Zhang, J., and Zhu, Y. (2022). Effect of B2O3 on the Radiation Shielding Performance of Telluride Lead Glass System. Crystals, 12.10.3390/cryst12020178 ↗
39. Al-Fakeh, M.S., Saleh, E.E., and Alresheedi, F. (2023). Synthesis of Novel Li2O-CuO-Bi2O3-B2O3 Glasses for Radiation Protection: An Experimental and Theoretical Study. Inorganics, 11.10.3390/inorganics11010027 ↗