SiO_{x} Based Anodes for Advanced Li‐Ion Batteries: Recent Progress and Perspectives

Guijuan Xie; Xu Tan; Zezhong Shi; Yi Peng; Yuan Ma; Yiren Zhong; Faxing Wang; Jiarui He; Zhi Zhu; Xin‐Bing Cheng; Gaojun Wang; Tao Wang; Yuping Wu

doi:10.1002/adfm.202414714

journal article·2025-02

SiO_x Based Anodes for Advanced Li‐Ion Batteries: Recent Progress and Perspectives

Guijuan Xie, Xu Tan, Zezhong Shi, Yi Peng, Yuan Ma, Yiren Zhong, Faxing Wang, Jiarui He, Zhi Zhu, Xin‐Bing Cheng, Gaojun Wang, Tao Wang, Yuping Wu

Advanced Functional Materials· Volume 35· Issue 6

Publisher page

Source abstract

Abstract

Abstract SiO_x with high theoretical capacity is regarded as a promising high‐performance anode material for lithium‐ion batteries. The main problem is the dramatic volume expansion after lithiation and the inherent poor conductivity. Tackling these problems, extensive strategies are proposed for SiO_x‐based anode materials in order to pursue high initial Coulombic efficiency, high reversible capacity, and long cycle stability. In this review, the lithium storage mechanism, merits, and disadvantages of SiO_x will be introduced in detail. Significant progress about SiO_x in recent years and their detailed strategies are summarized. Finally, challenges and potential solutions in the development and application of SiO_x are proposed. This review aims to offer a reference for the research of anode materials associated with SiO_x and offer a good guide for the further improvements of SiO_x anode materials.

Source: crossref · Quality: baseline

Research context

Energy storage

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Chemistry and Chemical Engineering Shaoxing University Shaoxing 312000 P. R. China

Confucius Energy Storage Lab Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education Z Energy Storage Center & School of Energy and Environment Southeast University Nanjing 211189 P. R. China

Funding

National Natural Science Foundation of China · Fundamental Research Funds for Central Universities of the Central South University · Chongqing Municipal Key Research and Development Program of China

References (100+)

Show source-provided references

1. 10.1126/science.aam585210.1126/science.aam5852 ↗

2. 10.1038/ncomms1343210.1038/ncomms13432 ↗

3. 10.1038/s41586-023-06918-410.1038/s41586-023-06918-4 ↗

4. 10.1002/aenm.20210044810.1002/aenm.202100448 ↗

5. 10.1002/adma.20230352010.1002/adma.202303520 ↗

6. 10.1002/aenm.20240301110.1002/aenm.202403011 ↗

7. 10.1002/aenm.20240290010.1002/aenm.202402900 ↗

8. Zhan J. · Electr. Power Technol. Environ. Prot. · 2024 · 40 · 284

9. 10.1002/smll.20210264110.1002/smll.202102641 ↗

10. 10.20517/energymater.2023.8410.20517/energymater.2023.84 ↗

11. 10.1002/adfm.20210254610.1002/adfm.202102546 ↗

12. 10.1021/acsnano.1c0589810.1021/acsnano.1c05898 ↗

13. 10.1021/acsnano.6b0452210.1021/acsnano.6b04522 ↗

14. 10.1039/C6TA10631E10.1039/C6TA10631E ↗

15. 10.1016/j.cej.2022.13616610.1016/j.cej.2022.136166 ↗

16. 10.1002/adfm.20210114510.1002/adfm.202101145 ↗

17. 10.1002/aenm.20220234210.1002/aenm.202202342 ↗

18. 10.1002/adfm.20221336310.1002/adfm.202213363 ↗

19. 10.1016/j.pnsc.2023.02.00310.1016/j.pnsc.2023.02.003 ↗

20. 10.1016/j.cej.2023.14529410.1016/j.cej.2023.145294 ↗

21. 10.1149/1.201321010.1149/1.2013210 ↗

22. 10.1016/j.jpowsour.2011.01.05310.1016/j.jpowsour.2011.01.053 ↗

23. 10.26599/NRE.2023.912007710.26599/NRE.2023.9120077 ↗

24. 10.1016/j.jelechem.2011.08.01010.1016/j.jelechem.2011.08.010 ↗

25. 10.1038/ncomms1159110.1038/ncomms11591 ↗

26. 10.1016/j.mssp.2008.11.00510.1016/j.mssp.2008.11.005 ↗

27. 10.1039/C8CS00441B10.1039/C8CS00441B ↗

28. 10.1149/1.133923910.1149/1.1339239 ↗

29. 10.1016/S0167-2738(02)00362-410.1016/S0167-2738(02)00362-4 ↗

30. 10.2109/jcersj2.119.85510.2109/jcersj2.119.855 ↗

31. 10.1039/c3ta00045a10.1039/c3ta00045a ↗

32. 10.1002/adma.20240575110.1002/adma.202405751 ↗

33. 10.1149/1.245596310.1149/1.2455963 ↗

34. 10.1016/j.electacta.2013.11.15810.1016/j.electacta.2013.11.158 ↗

35. 10.1021/cm203419510.1021/cm2034195 ↗

36. 10.1021/acs.jpcc.5b1058910.1021/acs.jpcc.5b10589 ↗

37. 10.1016/j.jpowsour.2018.10.06510.1016/j.jpowsour.2018.10.065 ↗

38. 10.1016/j.nanoen.2019.03.07710.1016/j.nanoen.2019.03.077 ↗

39. 10.1021/acs.nanolett.7b0090610.1021/acs.nanolett.7b00906 ↗

40. 10.1016/j.jallcom.2020.15577410.1016/j.jallcom.2020.155774 ↗

41. 10.1016/j.nanoen.2020.10514310.1016/j.nanoen.2020.105143 ↗

42. 10.1039/C6CP06158C10.1039/C6CP06158C ↗

43. 10.1007/s40820-022-00790-z10.1007/s40820-022-00790-z ↗

44. 10.1039/D4EY00014E10.1039/D4EY00014E ↗

45. 10.1093/nsr/nwab05010.1093/nsr/nwab050 ↗

46. 10.1149/1.154394810.1149/1.1543948 ↗

47. 10.1021/acs.jpclett.9b0167010.1021/acs.jpclett.9b01670 ↗

48. 10.1016/j.est.2023.10935410.1016/j.est.2023.109354 ↗

49. Dang G. · J. Materiomics · 2024

50. Huang L.‐B. · Angew. Chem., Int. Ed. · 2024

51. 10.1016/j.jpowsour.2018.08.06510.1016/j.jpowsour.2018.08.065 ↗

52. 10.1126/science.122245310.1126/science.1222453 ↗

53. 10.1021/cr050569o10.1021/cr050569o ↗

54. 10.1016/j.est.2024.11144510.1016/j.est.2024.111445 ↗

55. 10.1016/j.est.2023.10845210.1016/j.est.2023.108452 ↗

56. 10.1016/j.cej.2022.14082010.1016/j.cej.2022.140820 ↗

57. 10.1016/j.cej.2021.13106010.1016/j.cej.2021.131060 ↗

58. 10.1002/adfm.20210179610.1002/adfm.202101796 ↗

59. 10.1016/j.jpowsour.2021.23034110.1016/j.jpowsour.2021.230341 ↗

60. 10.1002/smll.20220213910.1002/smll.202202139 ↗

61. 10.1002/aenm.20210004610.1002/aenm.202100046 ↗

62. 10.1002/eom2.1240110.1002/eom2.12401 ↗

63. 10.1016/j.jechem.2021.04.06610.1016/j.jechem.2021.04.066 ↗

64. 10.1016/j.jelechem.2020.11473810.1016/j.jelechem.2020.114738 ↗

65. 10.1016/j.jpowsour.2016.03.11110.1016/j.jpowsour.2016.03.111 ↗

66. 10.1002/smll.20240307010.1002/smll.202403070 ↗

67. 10.1002/smtd.20220162310.1002/smtd.202201623 ↗

68. 10.1002/smll.20230264410.1002/smll.202302644 ↗

69. 10.1016/j.cej.2023.14596010.1016/j.cej.2023.145960 ↗

70. Ge J. · J. Mater. Chem. A · 1928 · 2022 · 10

71. Zhang K. · Energy Mater · 2024 · 4

72. 10.1021/acsami.2c0529310.1021/acsami.2c05293 ↗

73. 10.1021/acs.jpclett.9b0233510.1021/acs.jpclett.9b02335 ↗

74. 10.1016/j.carbon.2021.03.01110.1016/j.carbon.2021.03.011 ↗

75. 10.1016/j.cej.2024.14935910.1016/j.cej.2024.149359 ↗

76. 10.1016/j.ensm.2020.07.02710.1016/j.ensm.2020.07.027 ↗

77. 10.1002/adfm.20210031110.1002/adfm.202100311 ↗

78. 10.1016/j.cej.2021.12975410.1016/j.cej.2021.129754 ↗

79. 10.1021/acs.nanolett.9b0099610.1021/acs.nanolett.9b00996 ↗

80. 10.1002/smll.20231090710.1002/smll.202310907 ↗

81. 10.1002/advs.20220608410.1002/advs.202206084 ↗

82. 10.1021/acsenergylett.2c0217910.1021/acsenergylett.2c02179 ↗

83. 10.1002/adma.20200709010.1002/adma.202007090 ↗

84. 10.1002/adfm.20210724610.1002/adfm.202107246 ↗

85. 10.1002/cey2.17610.1002/cey2.176 ↗

86. 10.1002/adma.20230650410.1002/adma.202306504 ↗

87. 10.1002/adfm.20210413510.1002/adfm.202104135 ↗

88. 10.1021/acsami.0c1967310.1021/acsami.0c19673 ↗

89. 10.1021/acsaem.3c0199810.1021/acsaem.3c01998 ↗

90. 10.1016/j.mtener.2022.10109010.1016/j.mtener.2022.101090 ↗

91. 10.1016/j.cej.2022.13756310.1016/j.cej.2022.137563 ↗

92. 10.1016/j.jhazmat.2021.12548010.1016/j.jhazmat.2021.125480 ↗

93. 10.1021/acsami.3c0956110.1021/acsami.3c09561 ↗

94. 10.1039/D2GC01770A10.1039/D2GC01770A ↗

95. 10.1002/smtd.20210105210.1002/smtd.202101052 ↗

96. 10.1002/smll.20210392610.1002/smll.202103926 ↗

97. 10.1016/j.jcis.2021.11.09910.1016/j.jcis.2021.11.099 ↗

98. 10.1016/j.carbon.2021.04.04310.1016/j.carbon.2021.04.043 ↗

99. 10.1007/s40843-021-1708-610.1007/s40843-021-1708-6 ↗

100. 10.1016/j.jcis.2022.07.18610.1016/j.jcis.2022.07.186 ↗