A Semi‐Liquid Electrode toward Stable Zn Powder Anode

Abstract Zn powder anode possesses great versatility compared to the Zn foil counterpart, but the rough surface with a high surface area aggravates the corrosion and dendrite growth. Herein, a dendrite‐free and anti‐corrosive semi‐liquid Zn anode (SLA) is successfully fabricated based on Zn powder and a thickening agent. Benefiting from the rheological property, the unique anode effectively releases the stress induced by Zn plating, especially under high‐current densities. Meanwhile, the dual‐conductive medium, i.e., ionic and electronic, homogenizes the ion flux and allows the stripping/plating to occur within the entire anode. In a symmetric cell, the SLA anode exhibits stable electrochemical behavior with a prolonged lifespan at the current density of 5 mA cm⁻²/10 mA cm⁻² under the capacity of 5 mAh cm⁻²/10 mAh cm⁻². Improved durability of more than 5000 cycles is endowed when assembling an SLA anode with a vanadium‐based cathode. This study provides an electrode rheology‐based approach to overcome the stability challenge of powder anode for scale‐up manufacturing.