journal article·2017-03-30Open access

Epitaxial Defects in Nanoscale InP Fin Structures Revealed by Wet-Chemical Etching

Dennis van Dorp, Manuel Mannarino, Sophia Arnauts, Hugo Bender, Clement Merckling, Alain Moussa, Wilfried Vandervorst, Andreas Schulze

Crystals· Volume 7· Issue 4

Abstract

In this work, we report on wet-chemical defect revealing in InP fin structures relevant for device manufacturing. Both HCl and HBr solutions were explored using bulk InP as a reference. A distinct difference in pit morphology was observed between the two acids, attributed to an anisotropy in step edge reactivity. The morphology of the etch pits in bulk InP suggests that the dislocations are oriented mainly perpendicular to the surface. By studying the influence of the acid concentration on the InP fin recess in nanoscale trenches, it was found that aqueous HCl solution was most suitable for revealing defects. Planar defects in InP fin structures grown by the aspect ratio trapping technique could be visualized as characteristic shallow grooves approximately one nanometer deep. It is challenging to reveal defects in wide-field InP fins. In these structures, dislocations also reach the surface next to stack faults or twinning planes. Due to the inclined nature, dislocation-related pits are only a few atomic layers deep. Extending the pits is limited by the high reactivity of the fin sides and the strong surface roughening during etching. The process window for revealing wet-chemical defects in InP fins is limited.
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Research context

OpenAlex topics: Integrated Circuits and Semiconductor Failure Analysis · Semiconductor materials and devices · Nanowire Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Imec Kapeldreef 75, B-3001 Leuven, Belgium

Katholieke Universiteit Leuven, Celestijnenlaan, 200F B-3001 Leuven, Belgium

References (40)

Show source-provided references
1. Ultimate scaling of CMOS logic devices with Ge and III–V materials10.1557/mrs2009.136 ↗
2. Nanometre-scale electronics with III–V compound semiconductors10.1038/nature10677 ↗
3. Academic and industry research progress in germanium nanodevices10.1038/nature10678 ↗
4. Caymax, M., Eneman, G., Bellenger, F., Merckling, C., Delabie, A., Wang, G., Loo, R., Simoen, E., Mitard, J., and Jaeger, B.D. (2009). 2009 IEEE International Electron Devices Meeting (IEDM), IEEE.
5. Selective Growth of Strained Ge Channel on Relaxed SiGe Buffer in Shallow Trench Isolation for High Mobility Ge Planar and Fin p-FET10.1149/05009.0039ecst ↗
6. Loo, R., Sun, J., Witters, L., Hikavyy, A., Vincent, B., Shimura, Y., Favia, P., Richard, O., Bender, H., and Vandervorst, W. (2014, January 2–4). Strained Ge FinFET structures fabricated by selective epitaxial growth. Proceedings of the 2014 7th International Silicon-Germanium Technology and Device Meeting (ISTDM), Singapore.10.1109/ISTDM.2014.6874674 ↗
7. Heteroepitaxy of InP on Si(001) by selective-area metal organic vapor-phase epitaxy in sub-50 nm width trenches: The role of the nucleation layer and the recess engineering10.1063/1.4862044 ↗
8. III/V nano ridge structures for optical applications on patterned 300 mm silicon substrate10.1063/1.4961936 ↗
9. Site Selective Integration of III–V Materials on Si for Nanoscale Logic and Photonic Devices10.1021/cg300779v ↗
10. Study towards integration of In0.53Ga0.47As on 300 mm Si for CMOS sub-7 nm node: Development of thin graded InxGa1−xAs buffers on GaAs10.1016/j.jcrysgro.2016.04.014 ↗
11. Epitaxial necking in GaAs grown on pre-pattemed Si substrates10.1007/BF02665973 ↗
12. Defect reduction of GaAs/Si epitaxy by aspect ratio trapping10.1063/1.2924410 ↗
13. InP on Si(111): Accommodation of lattice mismatch and structural properties10.1063/1.111007 ↗
14. (Invited) Epitaxial Growth of Low Defect SiGe Buffer Layers for Integration of New Materials on 300 mm Silicon Wafers10.1149/05009.0613ecst ↗
15. Dislocations in Relaxed SiGe/Si Heterostructures10.1002/(SICI)1521-396X(199901)171:1<227::AID-PSSA227>3.0.CO;2-Y ↗
16. Quick Turnaround Technique for Highlighting Defects in Thin Si/SiGe Bilayers10.1149/1.1676116 ↗
17. Defect identification in strained Si/SiGe heterolayers for device applications10.1088/0022-3727/42/17/175306 ↗
18. A Review of Different and Promising Defect Etching Techniques: From Si to Ge10.1149/1.2773972 ↗
19. Revealing of defects in InP by shallow (submicron) photoetching10.1063/1.335715 ↗
20. Selective etching and photoetching of {100} gallium arsenide in CrO3-HF aqueous solutions: II. The nature of etchFF hillocks10.1016/0022-0248(83)90218-X ↗
21. HBr-K2Cr2O7-H2O etching system for indium phosphide10.1016/0022-0248(94)90092-2 ↗
22. Dhanaraj, G., Byrappa, K., Prasad, V., and Dudley, M. (2010). Springer Handbook of Crystal Growth, Springer.10.1007/978-3-540-74761-1 ↗
23. The mechanisms of the decomposition of semiconductors by electrochemical oxidation and reduction10.1016/0013-4686(68)80060-X ↗
24. Notten, P.H.L. (1992). Etching of III-V Semiconductors: An Electrochemical Approach, Elsevier Science Ltd.
25. The etching of InP in HCl solutions: A chemical mechanism10.1149/1.2115375 ↗
26. The electrochemistry of InP in Br2/HBr solutions and its relevance to etching behaviour10.1016/0169-4332(87)90135-8 ↗
27. Van Dorp, D.H., Deckers, J., Arnauts, S., and Kelly, J.J. Anisotropy in the surface chemistry of InP in acidic solutions, (In Preparation).
28. Room-temperature InP distributed feedback laser array directly grown on silicon10.1038/nphoton.2015.199 ↗
29. InGaAs Gate-All-Around Nanowire Devices on 300 mm Si Substrates10.1109/LED.2014.2359579 ↗
30. Wet Chemical Etching of Alignment V-Grooves in (100) InP through Titanium or In[sub 0.53]Ga[sub 0.47]As Masks10.1149/1.2054968 ↗
31. Effect of Etch Mask and Etching Solution on InP Micromachining to Form V-Grooves10.1149/1.1357177 ↗
32. Chemical Etching Characteristics of (001) InP10.1149/1.2127633 ↗
33. Pearsall, T.P. (2000). Properties, Processing and Applications of Indium Phosphide, Institution of Electrical Engineers.
34. Mahajan, S., and Moss, T.S. (1994). Handbook on Semiconductors: Materials, Properties, and Preparation, North-Holland Publishing Co.
35. Orthodox etching of HVPE-grown GaN10.1016/j.jcrysgro.2007.03.030 ↗
36. Sangwal: Etching of crystals; theory, experiment, and application, Volume 15 aus, der Reihe: Defects in Solids, (Eds.), S. Amelinckx—J. Nihoul, North-Holland, Amsterdam, Oxford, New York, Tokyo 1987. 497 Seiten, Preis: Dfl. 27510.1002/bbpc.19870911149 ↗
37. Amelinckx, S. (1964). The Observation of Dislocations, Academic Press.
38. Wet Chemical Etching of InP for Cleaning Applications: II. Oxide Removal10.1149/2.020304jss ↗
39. Study of InP Surfaces after Wet Chemical Treatments10.1149/2.005401jss ↗
40. Selective Area Growth of InP in Shallow-Trench-Isolated Structures on Off-Axis Si(001) Substrates10.1149/1.3489355 ↗