Solvent-Assisted Linker Exchange to Fabricate Pyrene-Modified MIL-125(Ti) for Enhancing the Visible-Light-Driven Generation of Reactive Oxygen Species
Source abstract
Abstract
Ti-oxide cluster-based metal–organic frameworks have shown great potential to fabricate multifunctional photocatalysts, but their catalytic activities often suffered from narrow light absorption and inefficient photogenerated charge separation. Herein, a solvent-assisted ligand exchange method was applied to functionalize MIL-125(Ti) with pyrene. Benefitting from the low energy triplet state of pyrene and efficient intersystem charge transfer between photosensitizers and Ti-oxide clusters, the functionalized MIL-125(Ti) showed enhancing visible-light adsorption and high photoactivity to give reactive oxygen species (•O 2 – and 1 O 2 ), which can be employed as a visible-light-driven photocatalyst for tetracycline degradation and aerobic oxidation of sulfides.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Nanomaterials in Catalysis · Analytical Chemistry and Sensors · Electrochemical sensors and biosensors
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, Changchun Normal University, Changchun 130032, China
Xiamen Institute of Rare-Earth Materials, Chinese Academy of Sciences, Xiamen 361005, China
State Key Laboratory of Structural Chemistry, Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350108, China
Funding
Natural Science Foundation of Jilin Province · Jilin Provincial Education Department · Natural Science Foundation of Changchun Normal University
References (49)
Show source-provided references
1. 10.1021/jacs.1c1336810.1021/jacs.1c13368 ↗
2. 10.1021/jacs.1c0796310.1021/jacs.1c07963 ↗
3. 10.1021/cr200324t10.1021/cr200324t ↗
4. 10.1039/D2TA07769H10.1039/D2TA07769H ↗
5. 10.1021/acsami.2c0394610.1021/acsami.2c03946 ↗
6. 10.1039/d0dt02143a10.1039/d0dt02143a ↗
7. 10.1002/anie.20220432610.1002/anie.202204326 ↗
8. 10.1021/acs.cgd.3c0111310.1021/acs.cgd.3c01113 ↗
9. 10.1002/anie.20221615910.1002/anie.202216159 ↗
10. 10.1021/acsestengg.1c0005110.1021/acsestengg.1c00051 ↗
11. 10.1039/d1ta08036a10.1039/d1ta08036a ↗
12. 10.1021/acssuschemeng.9b0482910.1021/acssuschemeng.9b04829 ↗
13. 10.1039/C3CC46398B10.1039/C3CC46398B ↗
14. 10.1002/anie.20180607710.1002/anie.201806077 ↗
15. 10.1039/C9QI01218D10.1039/C9QI01218D ↗
16. 10.1016/j.jcou.2021.10152810.1016/j.jcou.2021.101528 ↗
17. 10.1016/j.jcat.2019.08.03810.1016/j.jcat.2019.08.038 ↗
18. 10.1016/j.cej.2022.13941710.1016/j.cej.2022.139417 ↗
19. 10.1039/D3QI00472D10.1039/D3QI00472D ↗
20. 10.1021/acsami.8b1001010.1021/acsami.8b10010 ↗
21. 10.1039/D0TA06028C10.1039/D0TA06028C ↗
22. 10.1016/j.jallcom.2020.15716610.1016/j.jallcom.2020.157166 ↗
23. 10.1021/acs.jpcc.9b0270910.1021/acs.jpcc.9b02709 ↗
24. 10.1021/acs.inorgchem.9b0220310.1021/acs.inorgchem.9b02203 ↗
25. 10.1002/anie.20221671910.1002/anie.202216719 ↗
26. 10.1039/c9sc03080h10.1039/c9sc03080h ↗
27. 10.1039/C6TA05903A10.1039/C6TA05903A ↗
28. 10.1002/ange.20221868810.1002/ange.202218688 ↗
29. 10.1016/S1010-6030(01)00507-X10.1016/S1010-6030(01)00507-X ↗
30. 10.1021/jp013675c10.1021/jp013675c ↗
31. 10.1039/D2TA09606D10.1039/D2TA09606D ↗
32. 10.1016/j.apcatb.2021.12009110.1016/j.apcatb.2021.120091 ↗
33. 10.1002/chem.20210346610.1002/chem.202103466 ↗
34. 10.1039/D0CS00424C10.1039/D0CS00424C ↗
35. 10.1021/ja903726m10.1021/ja903726m ↗
36. 10.1021/acsami.5b0353510.1021/acsami.5b03535 ↗
37. 10.1016/j.snb.2023.13392810.1016/j.snb.2023.133928 ↗
38. 10.1016/j.optmat.2023.11345610.1016/j.optmat.2023.113456 ↗
39. 10.1016/j.jcis.2021.08.18310.1016/j.jcis.2021.08.183 ↗
40. 10.1016/j.cej.2022.13924610.1016/j.cej.2022.139246 ↗
41. 10.1016/j.scitotenv.2022.15979510.1016/j.scitotenv.2022.159795 ↗
42. 10.1021/jacs.3c0558510.1021/jacs.3c05585 ↗
43. 10.1021/cr900147h10.1021/cr900147h ↗
44. 10.1021/cr990372u10.1021/cr990372u ↗
45. 10.1021/ja028276p10.1021/ja028276p ↗
46. 10.1021/acs.jpcc.2c0733310.1021/acs.jpcc.2c07333 ↗
47. 10.1021/acsami.2c2130410.1021/acsami.2c21304 ↗
48. 10.1039/D0GC01500H10.1039/D0GC01500H ↗
49. 10.1021/acscatal.3c0028410.1021/acscatal.3c00284 ↗