Crystal Structure and Characterization of Organic−Inorganic Hybridized Molecules with Molecular Zipper Structures and Two-Dimensional Grid Networks
Source abstract
Abstract
Three succinate−metal coordination polymers have been synthesized and characterized. The structure of Co(dmbpy)(H 2 O) 2 (C 4 H 4 O 4 ) (dmbpy = 4,4‘-dimethyl-2,2‘-bipyridine, C 4 H 4 O 4 = succinate; 1 ) contains zipperlike chains, which are constructed of Co(II), dmbpy, H 2 O, and bridging succinates. The structure of two isomorphous 2-D compounds, M(dpdo)(H 2 O) 2 (C 4 H 4 O 4 ) (M = Zn ( 2 ) or Mn ( 3 ), dpdo = 4,4‘-dipyridyl N, N ‘-dioxide), consists of grid networks of succinate−metal chains linked by dpdo.
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Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Crystallography and molecular interactions · Supramolecular Self-Assembly in Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, Faculty of Science, National University of Singapore, 3 Science Drive 3, Singapore 117543, and Department of Chemistry and Chemical Engineering, Southeast University, Nanjing, 210096, P. R. China
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