journal article·2006-10-01

An (8,3)-a 3D Coordination Network and Concomitant Three-Connected Supramolecular Isomers

Brian S. Luisi, Victor Ch. Kravtsov, Brian D. Moulton

Crystal Growth & Design· Volume 6· Issue 10
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Abstract

An unprecedented (8,3)-a 3D coordination network was synthesized using crystal engineering strategies as one of three concomitant supramolecular isomers of the general formula [Cu 2 (tae)(bipy) 2 ]·2NO 3 - · x S (bipy = 4,4‘-bipyridine; tae = dibasic tetraacetyl-ethane; S = solvent: H 2 O/MeOH). The (8,3)-a network yields optically active single crystals with 58% solvent-accessible volume, despite 4-fold interpenetration.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Magnetism in coordination complexes · Supramolecular Chemistry and Complexes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Brown University, Providence, Rhode Island 02906, and Institute of Applied Physics of the Academy of Sciences of R. Moldova, Academy Street 5, MD2028 Chisinau, R. Moldova

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