journal article·2018-08Open access

Corrosion and tribocorrosion behaviour of β-type Ti-Nb and Ti-Mo surfaces designed by diffusion treatments for biomedical applications

J. Ureña, S. Tsipas, A.M. Pinto, F. Toptan, E. Gordo, A. Jiménez-Morales

Corrosion Science· Volume 140

Abstract

Corrosion and tribocorrosion behaviour of modified Ti surfaces through thermochemical treatments has been studied. Electrochemical Impedance Spectroscopy (EIS) and reciprocating sliding tests using a ball-on-plate tribometer under 1 N load and alumina as counter-material were used to evaluate the influence of Nb and Mo on titanium corrosion and tribocorrosion properties. Ti-Nb and Ti-Mo surfaces exhibited better anticorrosive properties than CP-titanium. Under tribological action the modified Ti surfaces showed similar coefficient of friction and lower tendency to corrosion compared to CP-Ti. Furthermore, Nb diffusion increased the repassivation rate with respect to Ti and Ti-Mo surfaces due to its stable passive film.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Titanium Alloys Microstructure and Properties · Orthopaedic implants and arthroplasty · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (45)

Show source-provided references
1. Surface modifications for improved wear performance in artificial joints: a review10.1007/s11837-015-1543-0 ↗
2. Corrosion and surface modification on biocompatible metals: a review10.1016/j.msec.2017.04.102 ↗
3. Surface modifications of titanium materials for developing corrosion behavior in human body environment: a review10.1016/j.mspro.2014.07.144 ↗
4. Ti based biomaterials, the ultimate choice for orthopaedic implants – a review10.1016/j.pmatsci.2008.06.004 ↗
5. Advances in metals and alloys for joint replacement
6. Wear characteristics of metallic biomaterials: a review
7. Study of corrosion in biocompatible metals for implants: a review10.1016/j.jallcom.2017.01.196 ↗
8. Surface analysis and electrochemical behavior of Ti-20Zr alloy in simulated physiological fluids10.1016/j.mseb.2013.07.006 ↗
9. Wear and corrosion interactions on titanium in oral environment: literature review
10. Current advances in enhancement of wear and corrosion resistance of titanium alloys – a review
11. Properties of passive film formed on CP titanium, Ti–6Al–4V and Ti–13.4Al–29Nb alloys in simulated human body conditions10.1016/j.intermet.2004.10.001 ↗
12. Biomedical materials and techniques to improve the tribological, mechanical and biomedical properties of orthopedic implants – a review article10.1016/j.jallcom.2017.04.231 ↗
13. Biocompatibility of niobium coatings10.3390/coatings1010072 ↗
14. Metastable beta Ti-Nb-Mo alloys with improved corrosion resistance in saline solution10.1016/j.electacta.2014.06.021 ↗
15. Biofilms inducing ultra-low friction on titanium10.1177/0022034510378428 ↗
16. Corrosion-wear of b-Ti alloy TMZF (Ti-12Mo-6Zr-2Fe) in simulated body fluid10.1016/j.actbio.2016.07.008 ↗
17. Tribocorrosion properties of different type titanium alloys in simulated body fluid
18. Tribocorrosion behavior of β-type Ti-15Zr-based alloys10.1016/j.matlet.2016.05.045 ↗
19. Corrosion resistance of molybdenum nitride modified Ti6Al4V alloy in HCl solution10.1007/s11595-007-3358-5 ↗
20. Dry sliding wear behaviour of β-type Ti-Nb and Ti-Mo surfaces designed by diffusion treatments for biomedical applications
21. In-vitro study of the bioactivity and cytotoxicity response of Ti surfaces modified by Nb and Mo diffusion treatments10.1016/j.surfcoat.2017.12.009 ↗
22. Cellular behaviour of bone marrow stromal cells on modified Ti-Nb surfaces10.1016/j.matdes.2017.12.006 ↗
23. Surface modification of powder metallurgy titanium by colloidal techniques and diffusion processes for biomedical applications10.1002/adem.201600207 ↗
24. Role of beta-stabilizer elements in microstructure and mechanical properties evolution of PM modified Ti surfaces designed for biomedical applications10.1080/00325899.2018.1426185 ↗
25. Tribocorrosion behaviour of hot pressed CoCrMo-HAP biocomposites10.1016/j.triboint.2015.04.009 ↗
26. Corrosion and tribocorrosion behaviour of Al-Si-Cu-Mg alloy and its composites reinforced with B4C particles in 0.05M NaCl solution10.1016/j.wear.2013.06.026 ↗
27. Molybdeno-aluminizing of powder metallurgy and wrought Ti and Ti-6Al-4V alloys by pack cementation process10.1016/j.matchar.2016.06.028 ↗
28. Electrochemical characterization of cast titanium alloys10.1016/S0142-9612(02)00293-4 ↗
29. Electrochemical stability and corrosion resistance of Ti-Mo alloys for biomedical applications10.1016/j.actbio.2008.07.010 ↗
30. Oxidation and corrosion protection by halide treatment of powder metallurgy Ti and Ti6Al4V alloy10.1016/j.corsci.2014.07.037 ↗
31. Microstructural and mechanical properties, surface and electrochemical characterisation of a new Ti-Zr-Nb alloy for implant applications10.1016/j.jallcom.2014.05.159 ↗
32. Is niobium more corrosion-resistant than commercially pure titanium in fluoride-containing artificial saliva?10.1016/j.electacta.2017.03.015 ↗
33. Electrochemical comparative study on corrosion behavior of conventional and powder metallurgy titanium alloys in physiological conditions10.1016/j.mprp.2016.04.003 ↗
34. Effect of heat treatment of magnesium alloy substrates on corrosion resistance of a hybrid organic–inorganic sol–gel film10.1039/C5RA16785J ↗
35. On the use of the power-law model for interpreting constant-phase-element parameters
36. Analysis and mitigation of the artefacts in electrochemical impedance spectroscopy due to three-electrode geometry10.1016/j.electacta.2014.05.011 ↗
37. Effect of Nb on the microstructure, mechanical properties, corrosion behavior, and cytotoxicity of Ti-Nb alloys10.3390/ma8095287 ↗
38. Dry sliding and tribocorrosion behaviour of hot pressed CoCrMo biomedical alloy as compared with the cast CoCrMo and Ti6Al4V alloys10.1016/j.matdes.2013.05.032 ↗
39. Simultaneous degradation by corrosion and wear of titanium in artificial saliva containing fluorides10.1016/j.wear.2012.05.030 ↗
40. Development of Ti–C–N coatings with improved tribological behavior and antibacterial properties10.1016/j.jmbbm.2015.10.020 ↗
41. A study of the potentials achieved during mechanical abrasion and the repassivation rate of titanium and Ti6Al4V in inorganic buffer solutions and bovine serum10.1016/j.electacta.2004.07.024 ↗
42. Repassivation of titanium and surface oxide film regenerated in simulated bioliquid10.1002/(SICI)1097-4636(19980615)40:4<530::AID-JBM3>3.0.CO;2-G ↗
43. Tribological behavior of plasma Mo–N surface modified Ti–6Al–4V alloy10.1016/S0257-8972(03)00855-7 ↗
44. Landolt · 2011
45. Tribological behaviors of Ti-6Al-4V alloy with surface plasma molybdenized layer10.1016/j.surfcoat.2012.05.134 ↗