journal article·2025-05

A bimodified MgAlCe-LDHs@GO self-healing anti-corrosion coating based on the micro arc oxidation coating of AZ31 magnesium alloy

Zuojun Jiao, Yan Zhou, Xiaowei Dai, Jiahao Wu, Yonghua Chen, Mingyi Wu, Wenhui Yao, Yuan Yuan, Zhihui Xie, Yanlong Ma, Atrens Andrej, Liang Wu

Corrosion Science· Volume 248
Publisher page

Abstract

To obtain magnesium (Mg) alloys with long-term corrosion resistance, coatings with enhanced stability and selfhealing effect are necessary. This study in-situ produced a layered double hydroxides (LDHs) coating using hydrothermal method to process the cerium salt treated micro arc oxidation (MAO) coating in sodium dodecylbenzene sulfonate (SDBS)-modified graphene oxide (GO) solution (MgAlCe-LDHs@GO-SDBS), and further introduced 3,5-dinitrosalicylic (D) acid and quinolizic acid (Q) via anion-exchange method. The multiple effects of Ce, GO-SDBS, and corrosion inhibitors significantly enhanced the coatings' anti-corrosive and self-healing performance. The MgAlCe-LDHs@GO-S&D coating possessed significantly decreased corrosion current density of 3.6 x 10-9 A center dot cm-2.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Layered Double Hydroxides Synthesis and Applications · Magnesium Oxide Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (53)

Show source-provided references
1. High-throughput characterization of microstructure and corrosion behavior of additively manufactured SS316L-SS431 graded material
2. Magnesium implants: prospects and challenges10.3390/ma12010136 ↗
3. A review of current challenges and prospects of magnesium and its alloy for bone implant applications10.1007/s40204-022-00182-x ↗
4. Latest research advances on magnesium and magnesium alloys worldwide10.1016/j.jma.2020.02.003 ↗
5. ZnAl-LDH@MXene modified by inhibitor as a nanofiller applied on Mg alloys coating protection10.1016/j.carbon.2022.12.008 ↗
6. Dual self-healing effects of salicylate intercalated MgAlY-LDHs film in-situ grown on the micro-arc oxidation coating on AZ31 alloys10.1016/j.corsci.2023.111285 ↗
7. A review of metal-organic framework protective coatings for light metals10.1080/02670844.2022.2161230 ↗
8. Corrosion mechanisms of magnesium alloys10.1002/(SICI)1527-2648(199909)1:1<11::AID-ADEM11>3.0.CO;2-N ↗
9. Review of Mg alloy corrosion rates10.1016/j.jma.2020.08.002 ↗
10. Anodic hydrogen evolution on Mg10.1016/j.jma.2021.09.002 ↗
11. Corrosion behavior of magnesium in aqueous sulfate-containing electrolytes10.1016/j.jma.2023.06.001 ↗
12. Corrosion and corrosion-fatigue behavior of magnesium metal matrix composites for bio-implant applications: a review10.1016/j.jma.2023.04.010 ↗
13. Plasma electrolytic oxidation of magnesium and its alloys: mechanism, properties and applications10.1016/j.jma.2017.02.004 ↗
14. Active corrosion protection by a smart coating based on a MgAl-layered double hydroxide on a cerium-modified plasma electrolytic oxidation coating on Mg alloy AZ3110.1016/j.corsci.2018.05.010 ↗
15. Corrosion properties and surface free energy of the ZnAl LDH/rGO coating on MAO pretreated AZ31 magnesium alloy10.1016/j.surfcoat.2021.127764 ↗
16. Layered double hydroxide coatings on magnesium alloys: a review10.1016/j.jmst.2018.03.003 ↗
17. Smart” micro/nano container-based self-healing coatings on magnesium alloys: a review10.1016/j.jma.2023.06.006 ↗
18. Development of anti-corrosive coating on AZ31 Mg alloy modified by MOF/LDH/PEO hybrids10.1016/j.jma.2023.12.004 ↗
19. Fabricating epoxy composite coating having self-healing/barrier anti-corrosion functions utilizing ion-exchange/pH-sensitive phosphate-doped ZIF8 MOF decorated Zn-Al-LDH nano-layers10.1016/j.surfcoat.2023.130284 ↗
20. Insight into ion exchange behavior of LDHs: asynchronous chloride adsorption and intercalated ions release processes10.1016/j.cemconcomp.2024.105433 ↗
21. Enhancement of corrosion resistance of AZ31 Mg alloys by one-step in situ synthesis of ZnAl-LDH films intercalated with organic anions (ASP, La)10.1016/j.jma.2020.03.013 ↗
22. Study on the corrosion and self-healing behavior of different anion-intercalated layered double hydroxides coatings on Mg alloy surfaces
23. Mechanochemical approaches to synthesize layered double hydroxides: a review10.1016/j.clay.2015.10.018 ↗
24. Effects of deformation processes on morphology, microstructure and corrosion resistance of LDHs films on magnesium alloy AZ3110.1016/j.jmst.2019.10.007 ↗
25. Comparison between the inhibition efficiencies of Ce(III) and Ce(IV) ammonium nitrates against corrosion of AA2024 aluminum alloy in solutions of low chloride concentration10.1016/j.corsci.2012.03.039 ↗
26. Design of self-healing PEO-based protective layers containing in-situ grown LDH loaded with inhibitor on the MA8 magnesium alloy10.1016/j.jma.2023.07.016 ↗
27. Benzoate intercalated Mg-Al-layered double hydroxides (LDHs) as efficient chloride traps for plasma electrolysis coatings10.1016/j.jallcom.2019.02.124 ↗
28. The effect of cerium cation on the microstructure and anti-corrosion performance of LDH conversion coatings on AZ31 magnesium alloy10.1016/j.jallcom.2019.153248 ↗
29. Double-doped LDH films on aluminum alloys for active protection10.1016/j.matlet.2017.01.038 ↗
30. Zinc aluminum-layered double hydroxide(LDH)-graphene oxide(GO) lubricating and corrosion-resistant composite coating on the surface of magnesium alloy10.1016/j.surfcoat.2022.128354 ↗
31. A self-healing corrosion protection coating with graphene oxide carrying 8-hydroxyquinoline doped in layered double hydroxide on a micro-arc oxidation coating10.1016/j.corsci.2021.109941 ↗
32. Synergistic effect on corrosion inhibition of copper by sodium dodecylbenzenesulphonate (SDBS) and 2-mercaptobenzoxazole10.1016/j.matchemphys.2007.11.018 ↗
33. Synergism between rare earth cerium(IV) ion and vanillin on the corrosion of steel in H2SO4 solution: Weight loss, electrochemical, UV–vis, FTIR, XPS, and AFM approaches10.1016/j.apsusc.2008.03.026 ↗
34. Composite membranes based on sulfonated poly(ether ether ketone) and SDBS-adsorbed graphene oxide for direct methanol fuel cells10.1039/c2jm35571j ↗
35. In situ surface film evolution during Mg aqueous corrosion in presence of selected carboxylates10.1016/j.corsci.2020.108484 ↗
36. Corrosion inhibition of WE43 Mg alloy by salicylic compounds: Influence of nitro substitution10.1016/j.corsci.2024.112558 ↗
37. Enhanced corrosion protective performance of graphene oxide-based composite films on AZ31 magnesium alloys in 3.5 wt% NaCl solution10.1016/j.apsusc.2019.07.101 ↗
38. Preparation technology and properties of a thin anodic oxide composite film on the surface of an aluminum alloy foil10.1016/j.surfcoat.2022.128825 ↗
39. Fabrication and characterization of Mg-M layered double hydroxide films on anodized magnesium alloy AZ3110.1016/j.apsusc.2017.06.244 ↗
40. Eco-friendly approach for effective removal for Congo red dye from wastewater using reusable Zn-Al layered double hydroxide anchored on multiwalled carbon nanotubes supported sodium dodecyl sulfonate composites10.1016/j.molliq.2022.118468 ↗
41. Synthesis of graphene oxide nanosheets functionalized by green corrosion inhibitive compounds to fabricate a protective system10.1016/j.corsci.2017.08.029 ↗
42. Pickering emulsion template method induced highly oriented functionalized graphene oxide in PDMS composites to achieve high gas barrier properties10.1016/j.polymer.2021.124273 ↗
43. A magnetic organic–inorganic composite: Synthesis and characterization of magnetic 5-aminosalicylic acid intercalated layered double hydroxides10.1016/j.jssc.2005.09.008 ↗
44. Polyelectrolyte-modified layered double hydroxide nanocontainers as vehicles for combined inhibitors10.1039/C5RA03741G ↗
45. Deposition and characterization of cerium oxide conversion coatings on aluminum alloy 7075-T610.1016/S0257-8972(03)00742-4 ↗
46. High effective organic corrosion inhibitors for 2024 aluminium alloy10.1016/j.electacta.2007.05.058 ↗
47. N 1s orbital binding energies of some pyrazole pyrazoline compounds by XPS10.1016/0368-2048(83)85079-8 ↗
48. One-step in situ synthesis of graphene oxide/MgAl-layered double hydroxide coating on a micro-arc oxidation coating for enhanced corrosion protection of magnesium alloys10.1016/j.surfcoat.2021.127083 ↗
49. Permanent agglomerates in powdered nanoparticles: Formation and future prospects10.1016/j.powtec.2017.09.042 ↗
50. Susceptibility of rare-earth-magnesium alloys to micro-galvanic corrosion10.1016/j.corsci.2010.08.006 ↗
51. Effect of electrolyte additives on performance of plasma electrolytic oxidation films formed on magnesium alloy AZ91D10.1016/j.electacta.2006.10.066 ↗
52. Electrochemical behaviour of the MA8 Mg alloy in minimum essential medium10.1016/j.corsci.2020.108552 ↗
53. An hydrogen evolution method for the estimation of the oxide scale growth on reactor alloys in supercritical water10.1016/j.jnucmat.2017.07.052 ↗