journal article·2025-09Open access

Improving Surface Quality of Titanium Electrodeposition from a Deep Eutectic Solvent with Organic and Inorganic Additives

Steven Livers, Christopher Chancellor, Katarzyna Grubel, Diana Horangic, Riah Burnett, Bailey Byrd, Christina Arendt, Lance Hubbard

Advanced Engineering Materials· Volume 27· Issue 18

Abstract

Titanium electroreduction is desired for a variety of medical, electronic, and bonding applications but has not been possible until recently. Titanium electrodeposition with leveler and brightener additives in the deep eutectic solvent ethaline has been studied for effects on spectroscopic reflectance. Polymeric leveling agents and several small‐molecule brighteners produce level/bright films (respectively) with high values for both specular and diffuse reflectance. The application of these leveling and brightening agents can produce films with appearances and surface roughnesses that may be suitable for application in medical implants such as stents, corrosion protection of electronics for wearable technology, and as interlayers between dissimilar metals.
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Research context

OpenAlex topics: Electrochemical Analysis and Applications · Ionic liquids properties and applications · Electrodeposition and Electroless Coatings

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Security Directorate Pacific Northwest National Laboratory Richland WA 99354 USA

Department of Chemistry Alabama State University Montgomery Al USA

Q‐20 Los Alamos National Laboratory Los Alamos NM 87544 USA

References (11)

Show source-provided references
1. L.Hubbard C. A.Arendt R.Webster Composition and method embodiments for plating metal coatings US11613825 2023 https://www.osti.gov/servlets/purl/1987259.
2. L. R.Hubbard C. L.Arendt B. M.Lawler Electroplating Titanium from Ionic Mixtures No. PNNL‐32787. Pacific Northwest National Laboratory (PNNL) Richland WA (United States) 2021 https://www.osti.gov/servlets/purl/1989052.
3. 10.1039/C6CP08720E10.1039/C6CP08720E ↗
4. Sibrell P. L. · 1995 · 9592
5. 10.1039/b800353j10.1039/b800353j ↗
6. 10.1007/s11356-020-11144-w10.1007/s11356-020-11144-w ↗
7. 10.1016/j.arabjc.2021.10303610.1016/j.arabjc.2021.103036 ↗
8. 10.1016/j.surfcoat.2022.12861010.1016/j.surfcoat.2022.128610 ↗
9. 10.1016/j.electacta.2019.02.09010.1016/j.electacta.2019.02.090 ↗
10. 10.1007/s10800-013-0608-410.1007/s10800-013-0608-4 ↗
11. 10.1080/00202967.2004.1187154710.1080/00202967.2004.11871547 ↗