journal article·2023-11

Improvement of carbon dots corrosion inhibition by ionic liquid modification: Experimental and computational investigations

Feng-Ting Li, Zhi-Kun Wang, Yi Zhou, Li-Zhi Li, Yue-Qi Liu, Li Wang, Chun-Ling Li, Hua-Feng Zhu, Shuang-Qing Sun, Song-Qing Hu

Corrosion Science· Volume 224
Publisher page

Abstract

Chemical modification is effective in improving the corrosion inhibition efficiency of carbon dots (CDs) on steel. Here, the imidazolium ionic liquids (IL) modified-CDs (IL-CDs) are synthesized and proved to be mixed-type corrosion inhibitors. The IL increases the pyrrole N content and facilitates the formation of a denser inhibitor film. Molecular simulations confirm that the IL reduces the π-π interaction between CDs, endowing IL-CDs with higher water solubility and better corrosion inhibition effect than CDs. The lower orbital energy gap and larger positive electrostatic potential distribution enable the inhibition efficiency of IL-CDs of 97.11% in 1 M HCl, much superior to CDs (90.80%).
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon and Quantum Dots Applications · ZnO doping and properties · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Bolaamphiphile-class surfactants as corrosion inhibitor model compounds against acid corrosion of mild steel10.1016/j.molliq.2020.113070 ↗
2. Galactomannan as a new bio-sourced corrosion inhibitor for iron in acidic media10.1016/j.heliyon.2020.e03574 ↗
3. Evaluation of 2-mercaptobenzimidazole derivatives as corrosion inhibitors for mild steel in hydrochloric acid10.3390/met10030357 ↗
4. Novel sucrose derivative as a thermally stable inhibitor for mild steel corrosion in 15% HCl medium: an experimental and computational study10.1016/j.cej.2022.136938 ↗
5. Neutral inhibitor molecules entrapped into polypyrrole network for corrosion protection10.1016/j.cej.2022.135739 ↗
6. Frontiers and advances in green and sustainable inhibitors for corrosion applications: a critical review10.1016/j.molliq.2020.114385 ↗
7. A comparative electrochemical and quantum chemical calculation study of BTAH and BTAOH as copper corrosion inhibitors in near neutral chloride solution10.1016/j.electacta.2008.06.061 ↗
8. Hydrogen evolution on copper in H2SO4 containing benzotriazole10.5006/0010-9312-28.9.345 ↗
9. Organic compounds as corrosion inhibitors in different environments-a review10.1016/0033-0655(81)80009-X ↗
10. Synthesis and corrosion inhibition of α-amino acids alkylamides for mild steel in acidic environment10.1016/j.matchemphys.2008.02.010 ↗
11. Investigation of the inhibition effect of indole-3-carboxylic acid on the copper corrosion in 0.5 M H2SO410.1016/j.corsci.2008.09.032 ↗
12. Chitosan derivative corrosion inhibitor for aluminum alloy in sodium chloride solution: A green organic/inorganic hybrid10.1016/j.carbpol.2021.118074 ↗
13. Electronic effect vs. Molecular size effect: experimental and computational based designing of potential corrosion inhibitors10.1016/j.cej.2021.132645 ↗
14. Efficiency of a novel multifunctional corrosion inhibitor against biofilms developed on carbon steel10.3389/fbioe.2022.803559 ↗
15. Neutral inhibitor molecules entrapped into polypyrrole network for corrosion protection10.1016/j.cej.2022.135739 ↗
16. Ionic liquids as green and sustainable steel corrosion inhibitors: recent developments10.1016/j.cej.2021.131480 ↗
17. Glycyrrhiza glabra leaves extract as a green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution: experimental, molecular dynamics, Monte Carlo and quantum mechanics study10.1016/j.molliq.2018.01.144 ↗
18. The recent development of carbon dots as powerful green corrosion inhibitors: a prospective review
19. Carbon dots as environment-friendly and efficient corrosion inhibitors for Q235 steel in 1 M HCl10.1021/acs.langmuir.1c02182 ↗
20. Corrosion inhibition behavior and mechanism of N-doped carbon dots for metal in acid environment10.1016/j.jclepro.2020.122458 ↗
21. An effective corrosion inhibitor of N doped carbon dots for Q235 steel in 1 M HCl solution10.1016/j.jallcom.2019.152338 ↗
22. Evaluation of the inhibition behavior of carbon dots on carbon steel in HCl and NaCl solutions10.1016/j.jmst.2020.01.025 ↗
23. A high-efficiency corrosion inhibitor of N-doped citric acid-based carbon dots for mild steel in hydrochloric acid environment10.1016/j.jhazmat.2019.121019 ↗
24. Ionic liquid-assisted preparation of N, S-rich carbon dots as efficient corrosion inhibitors10.1016/j.molliq.2022.118943 ↗
25. N, S co-doped carbon dots as effective corrosion inhibitor for carbon steel in CO2-saturated 3.5% NaCl solution10.1016/j.jtice.2019.02.036 ↗
26. Functionalization of citric acid-based carbon dots by imidazole toward novel green corrosion inhibitor for carbon steel10.1016/j.jclepro.2019.05.030 ↗
27. A green and effective corrosion inhibitor of functionalized carbon dots10.1016/j.jmst.2019.05.045 ↗
28. Covalent functionalization of polydisperse chemically-converted graphene sheets with amine-terminated ionic liquid10.1039/b905085j ↗
29. Strengthening of Mg based alloy through grain refinement for orthopaedic application10.1016/j.jmbbm.2015.12.010 ↗
30. Comparative studies on the corrosion inhibition characteristics of three different triazine based Schiff’s bases, HMMT, DHMMT and MHMMT, for mild steel exposed in sulfuric acid10.1016/j.ejpe.2017.07.011 ↗
31. Multiwfn: a multifunctional wavefunction analyzer10.1002/jcc.22885 ↗
32. Novel nitrogen doped carbon dots for corrosion inhibition of carbon steel in 1 M HCl solution10.1016/j.apsusc.2018.02.255 ↗
33. Carbon dots doped with N and S towards controlling emitting10.1007/s10895-019-02472-3 ↗
34. Graphitic nitrogen triggers red fluorescence in carbon dots10.1021/acsnano.7b06399 ↗
35. Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis10.1021/nn103584t ↗
36. Experimental and theoretical studies on the corrosion inhibition of mild steel by some sulphonamides in aqueous HCl10.1039/C4RA11414K ↗
37. Novel surfactants as green corrosion inhibitors for mild steel in 15% HCl: experimental and theoretical studies10.1016/j.cej.2020.126219 ↗
38. 2, 4-Diamino-5-(phenylthio)-5H-chromeno [2, 3-b] pyridine-3-carbonitriles as green and effective corrosion inhibitors: gravimetric, electrochemical, surface morphology and theoretical studies10.1039/C6RA04900A ↗
39. Assessment of the inhibition efficiency of 3, 4-diaminobenzonitrile against the corrosion of steel10.1016/j.corsci.2015.10.036 ↗
40. Probing the corrosion resistance of a smart electroless Ni-P composite coating embedded with pH-responsive corrosion inhibitor-loaded nanocapsules
41. Seed extract of Psidium guajava as ecofriendly corrosion inhibitor for carbon steel in hydrochloric acid medium10.1016/S1005-0302(12)60010-3 ↗
42. Polar group substituted imidazolium zwitterions as eco-friendly corrosion inhibitors for mild steel in acid solution10.1016/j.corsci.2020.108665 ↗
43. Glycogen nanoparticles as a potential corrosion inhibitor10.1016/j.ijbiomac.2021.05.185 ↗
44. Experimental and theoretical studies of benzothiazole derivatives as corrosion inhibitors for carbon steel in 1 M HCl10.1016/j.corsci.2016.08.012 ↗
45. Experimental and computational mediated illustration of effect of different substituents on adsorption tendency of phthalazinone derivatives on mild steel surface in acidic medium10.1016/j.molliq.2020.112844 ↗
46. In-depth insight into the inhibition mechanism of the modified and combined amino acids corrosion inhibitors: “intramolecular synergism” vs. “intermolecular synergism”10.1016/j.cej.2022.135439 ↗
47. COMPASS: an ab initio force-field optimized for condensed-phase applications overview with details on alkane and benzene compounds10.1021/jp980939v ↗
48. Molecular dynamic simulation and experimental investigation on the synergistic mechanism and synergistic effect of oleic acid imidazoline and l-cysteine corrosion inhibitors10.1016/j.corsci.2021.109414 ↗