journal article·2014-03

Effects of temperature and the incorporation of W on the oxidation of ZrB2 ceramics

M. Kazemzadeh Dehdashti, W.G. Fahrenholtz, G.E. Hilmas

Corrosion Science· Volume 80
Publisher page

Abstract

Abstract The effects of tungsten additions and temperature on the oxidation behavior of nominally pure ZrB 2 and ZrB 2 containing 4, 6 or 8 mol% of W after oxidation at temperatures ranging from 800 to 1600 °C were investigated. For pure ZrB 2 , the protective liquid/glassy layer covering the surface as a result of oxidation was evaporated above 1500 °C. For (Zr,W)B 2 specimens, the liquid/glassy layer was present after exposure up to 1600 °C. The higher stability of the liquid/glassy phase in the W-containing compositions was attributed to the presence of tungsten in the liquid/glassy phase, resulting in improved oxidation resistance for ZrB 2 samples containing W.
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Research context

OpenAlex topics: Advanced ceramic materials synthesis · Advanced materials and composites · Nuclear materials and radiation effects

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References (41)

Show source-provided references
1. Densification of ZrB2-based composites and their mechanical and physical properties: a review10.1016/j.jeurceramsoc.2008.11.008 ↗
2. Thermal and electrical transport properties of spark plasma-sintered HfB2 and ZrB2 ceramics10.1111/j.1551-2916.2011.04411.x ↗
3. Plasma wind tunnel testing of ultra-high temperature ZrB2–SiC composites under hypersonic ee-entry conditions10.1016/j.jeurceramsoc.2010.01.029 ↗
4. Evolution of structure during the oxidation of zirconium diboride–silicon carbide in air up to 1500°C10.1016/j.jeurceramsoc.2006.10.012 ↗
5. Refractory diborides of zirconium and hafnium10.1111/j.1551-2916.2007.01583.x ↗
6. The oxidation kinetics of zirconium diboride and zirconium carbide at high temperatures10.1149/1.2426263 ↗
7. Oxidation of ZrB2-based ceramics in dry air10.1149/1.1618226 ↗
8. High-temperature oxidation III. Zirconium and hafnium diborides10.1149/1.2424154 ↗
9. Thermogravimetric study of the oxidation of ZrB2 in the temperature range of 800° to 1500°C10.1149/1.2408279 ↗
10. The oxidation of titanium diboride and zirconium diboride at high temperatures10.1016/0022-5088(68)90067-2 ↗
11. Improved oxidation resistance of zirconium diboride by tungsten carbide additions10.1111/j.1551-2916.2008.02713.x ↗
12. A model for the oxidation of ZrB2, HfB2 and TiB210.1016/j.actamat.2007.07.027 ↗
13. T.A. Parthasarathy, R.A. Rapp, M. Opeka, R.J. Kerans, A model for transitions in oxidation regimes of ZrB2, in: Les Embiez, 2008, pp. 823–832.10.4028/www.scientific.net/MSF.595-598.823 ↗
14. Oxidation of zirconium diboride–silicon carbide at 1500°C in a low partial pressure of oxygen10.1111/j.1551-2916.2006.01229.x ↗
15. Oxidation behavior of zirconium diboride silicon carbide produced by the spark plasma sintering method10.1111/j.1551-2916.2009.03134.x ↗
16. Oxidation resistance and strength retention of ZrB2–SiC ceramics10.1016/j.jeurceramsoc.2010.01.028 ↗
17. Dynamic oxidation of ultra-high temperature ZrB2–SiC under high enthalpy supersonic flows10.1016/j.corsci.2010.11.018 ↗
18. Preoxidation and crack-healing behavior of ZrB2–SiC ceramic composite10.1111/j.1551-2916.2008.02760.x ↗
19. Convection patterns in liquid oxide films on ZrB2–SiC composites oxidized at a high temperature10.1111/j.1551-2916.2007.01784.x ↗
20. I. Akin, F. Cinar Sahin, O. Yucel, G. Goller, Oxidation behavior of zirconium diboride–silicon carbide composites, in: 34th International Conference on Advanced Ceramics and Composites, Daytona Beach, FL, 2010, pp. 105–111.10.1002/9780470944066.ch10 ↗
21. Oxidation of ZrB2–SiC: influence of SiC content on solid and liquid oxide phase formation10.1111/j.1551-2916.2008.02874.x ↗
22. Oxidation behavior of hot pressed ZrB2–SiC and HfB2–SiC composites10.1016/j.jeurceramsoc.2010.08.018 ↗
23. E.J. Opila, M.C. Halbig, Oxidation of ZrB2–SiC, in: 25th Annual Conference on Composites, Advanced Ceramics, Materials and Structures, Cocoa Beach, FL, 2001, pp. 221–228.10.1002/9780470294680.ch27 ↗
24. Oxidation behavior of ZrB2–MoSi2–SiC composites in air at 1500°C10.1016/j.ceramint.2010.09.034 ↗
25. A.L. Chamberlain, W.G. Fahrenholtz, G.E. Hilmas, D.T. Ellerby, Characterization of zirconium diboride for thermal protection systems, in: 8th Conference and Exhibition of the European Ceramic Society, Istanbul, Turkey, 2004, pp. 493–496.10.4028/www.scientific.net/KEM.264-268.493 ↗
26. Oxidation behavior of a pressureless sintered ZrB2–MoSi2 ceramic composite10.1557/JMR.2005.0111 ↗
27. High-temperature chemistry and oxidation of ZrB2 ceramics containing SiC, Si3N4, Ta5Si3, and TaSi210.1111/j.1551-2916.2008.02420.x ↗
28. Oxidation behaviour of HfB2-15vol.% TaSi2 at low, intermediate and high temperatures10.1016/j.scriptamat.2010.05.050 ↗
29. Oxidation-based materials selection for 2000°C+hypersonic aerosurfaces: theoretical considerations and historical experience10.1023/B:JMSC.0000041686.21788.77 ↗
30. Oxidation of ZrB2-based ultra-high temperature ceramics10.1002/9780470294680.ch27 ↗
31. S.R. Levine, E.J. Opila, Tantalum Addition to Zirconium Diboride for Improved Oxidation Resistance, in: NASA/TM-2003-212483, 2003.
32. Effect of SiC, TaB2 and TaSi2 additives on the isothermal oxidation resistance of fully dense zirconium diboride
33. Oxidation of ZrB2 ceramics modified with SiC and group IV–VI transition metal diborides
34. Effect of various additives on the oxidation behavior of ZrB2-based ultra-high-temperature ceramics at 1800°C10.1111/j.1551-2916.2009.03420.x ↗
35. The addition of lanthanum hexaboride to zirconium diboride for improved oxidation resistance10.1016/j.scriptamat.2007.07.036 ↗
36. Oxidation of zirconium diboride with tungsten carbide additions10.1111/j.1551-2916.2010.04216.x ↗
37. Condensed phase relations in the systems ZrO2–WO2–WO3 and HfO2–WO2–WO310.1111/j.1151-2916.1967.tb15084.x ↗
38. Zirconia transport by liquid convection during oxidation of zirconium diboride–silicon carbide10.1111/j.1551-2916.2007.02142.x ↗
40. Structural and optical properties of WO3–PbO–B2O3 glass-ceramic10.1016/j.jpcs.2011.12.004 ↗
41. Vogel · 1994