journal article·2022-12

A high-resolution study of the different surface state effects on the corrosion behaviors of a ferritic steel and an austenitic steel in supercritical water

K. Chen, J. Wang, L. Zhang, H. Wang, X. An, Y. Li, J. Zhang, Z. Shen, X. Zeng

Corrosion Science· Volume 209
Publisher page

Abstract

The corrosion behaviors of two iron-based steels in 600 ºC deaerated supercritical water (SCW) were investigated to study the effect of surface finishing. For the austenitic stainless steel (Fe-19Cr-9Ni), grinding significantly enhanced the oxidation resistance by favoring the formation of a thin and continuous chromia layer. This is because that grinding induced ultra-fined grain layer with a high dislocation density promotes the outward Cr diffusion, thus favors the transition from internal to external oxidation. For the ferritic steel (Fe-9Cr), the oxidation rate remained at a high level regardless of the surface condition mainly because the Cr diffusivity is already high enough but the Cr content is too low to promote the internal-external oxidation transition.
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Research context

OpenAlex topics: Subcritical and Supercritical Water Processes · High-Temperature Coating Behaviors · Advanced Materials Characterization Techniques

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