journal article·2026-02

Grain boundary versus grain interior aqueous corrosion in iron-phosphorous and iron-copper binary ferritic alloys

Rakesh Kumar Barik, Namit N. Pai, Arnab Sarkar, Vikram Chavan, Mohammad I. Khan, Hitesh Mehtani, Smrutiranjan Parida, Ajay S. Panwar, Indradev Samajdar

Corrosion Science· Volume 259
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OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · Microstructure and mechanical properties · Magnetic Properties and Applications

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References (96)

Show source-provided references
1. Ahmad · 2006
2. Schütze · 2016
3. Effects of Cr, Cu, Ni and Ca on the corrosion behavior of low carbon steel in synthetic tap water10.1016/j.jallcom.2004.07.081 ↗
4. Weathering steels: from empirical development to scientific design. A review10.1016/j.corsci.2014.03.006 ↗
5. Oxidation in iron–copper and iron–phosphorous binary alloys: relating alloying and metal-oxide crystallography with oxidation resistance10.1007/s11085-022-10099-2 ↗
6. Roberge · 2000
7. Effects of alloying elements on the corrosion of steel in industrial atmospheres10.5006/1.3290374 ↗
8. Effect of phosphorus on the corrosion behavior of carbon steel in sulfuric acid10.5006/1.3524835 ↗
9. Intergranular corrosion of iron-phosphorus alloys in nitrate solutions10.1016/0010-938X(81)90032-9 ↗
10. The effect of phosphorus on the mechanism of intergranular stress corrosion cracking of mild steels in nitrate solutions10.1016/0010-938X(88)90108-4 ↗
11. The dual nature of Cu content on the corrosion resistance of low alloy steels in sulfuric acid: A time-dependent reversal of corrosion resistance10.1016/j.corsci.2023.111486 ↗
12. Revealing the relationship between grain size and corrosion rate of metals10.1016/j.scriptamat.2010.08.035 ↗
13. Electrochemical behaviour and corrosion of Mg–Y alloys10.1016/j.corsci.2011.03.010 ↗
14. The defining role of plastic deformation on resistance to aqueous corrosion of interstitial free steel10.1007/s11661-021-06412-4 ↗
15. Corrosion resistance of the Dhar iron pillar10.1016/S0010-938X(03)00074-X ↗
16. India’s
17. Ancient Indian iron and steel and modern scientific insights
18. Effects of relative humidity on the corrosion of iron: an experimental view
19. Microstructure and aqueous corrosion in carbon steel: an emerging correlation10.1016/j.matchemphys.2022.126623 ↗
20. Characterization of rust on ancient Indian iron
21. Grain boundary nanochemistry and intergranular corrosion of Fe-0.01wt%P alloy: Roles of elemental segregations and misorientation10.1016/j.actamat.2024.120577 ↗
22. Phosphorus grain boundary segregation in steel 17-4 PH10.1016/S1359-6462(02)00310-X ↗
23. The defining role of interface crystallography in corrosion of a two-phase pearlitic steel10.1080/14786435.2020.1725247 ↗
24. Galvanic corrosion between the constituent phases in duplex stainless steel10.1016/j.corsci.2007.03.035 ↗
25. Influence of the secondary phase on micro galvanic corrosion of low carbon bainitic steel in NaCl solution10.1016/j.matchar.2018.03.021 ↗
26. Corrosion mechanism of advanced high strength dual-phase steels by electrochemical noise analysis in chloride solutions
27. Grain boundary character dependence of phosphorus segregation at ferrite grain boundaries in a high-purity iron-phosphorus binary alloy10.1016/j.scriptamat.2024.116170 ↗
28. Effect of grain boundary structure on sensitization and corrosion of stainless steel10.1007/BF02668561 ↗
29. Correlating the five parameter grain boundary character distribution and the intergranular corrosion behaviour of a stainless steel using 3D orientation microscopy based on mechanical polishing serial sectioning10.1016/j.actamat.2018.06.044 ↗
30. Measuring the five-parameter grain-boundary distribution from observations of planar sections10.1007/s11661-004-0147-z ↗
31. Distribution of grain boundaries in magnesia as a function of five macroscopic parameters10.1016/S1359-6454(03)00181-2 ↗
32. Theoretical and experimental grain boundary energies in body-centered cubic metals10.1016/j.actamat.2023.119074 ↗
33. ASTM G101-04, Standard Guide for Estimating the Atmospheric Corrosion Resistance of Low-Alloy Steels, ASTM Int. (2020) 1–8. https://doi.org/10.1520/G0101-04R20.2.
34. Standard reference test method for making potentiodynamic anodic polarization measurements
35. The effect of copper on passivity and corrosion behaviour of ferritic and ferritic–austenitic stainless steels10.1016/S0921-5093(99)00530-4 ↗
36. Understanding localized corrosion10.1016/S1369-7021(08)70206-2 ↗
37. A DFT study on corrosion mechanism of steel bar under water-oxygen interaction10.1016/j.commatsci.2019.109265 ↗
38. Applications of density functional theory to corrosion and corrosion prevention of metals: a review
39. A reactive molecular dynamics simulation study on corrosion behaviors of carbon steel in salt spray10.1016/j.commatsci.2021.111142 ↗
40. Atomic insight into iron corrosion exposed to supercritical water environment with an improved Fe-H2O reactive force field10.1016/j.apsusc.2021.152300 ↗
41. Atomistic simulation of initial stages of iron corrosion in pure water using reactive molecular dynamics10.1016/j.commatsci.2017.12.044 ↗
42. Oxidation mechanisms of (FeCr2 V) 92% W 8% medium entropy alloy for nuclear application: insight from Ab initio study10.1021/acs.langmuir.5c00628 ↗
43. Adsorption of a water molecule on Fe(100): density-functional calculations10.1103/PhysRevB.81.115460 ↗
44. An overview of molecular dynamic simulation for corrosion inhibition of ferrous metals10.3390/met11010046 ↗
45. Monte Carlo simulations of corrosion inhibition of mild steel in 0.5 M sulphuric acid by some green corrosion inhibitors10.1007/s10008-009-0845-y ↗
46. Computational experiments of metal corrosion studies: a review
47. Development and validation of a ReaxFF reactive force field for Fe/Al/Ni alloys: molecular dynamics study of elastic constants, diffusion, and segregation10.1021/jp308507x ↗
48. The ReaxFF reactive force-field: development, applications and future directions10.1038/npjcompumats.2015.11 ↗
49. Perspective on density functional theory10.1063/1.4704546 ↗
50. Verma · 2022
51. Snoek-dominated internal friction response in bcc steel: relating experiments with a multi-scale atomistic computational framework10.1007/s11661-022-06899-5 ↗
52. Plasticity induced anelasticity: the atomistic origin10.1016/j.ijplas.2024.103901 ↗
53. Introduction to the Kinetic Monte Carlo Method
54. ReaxFF: a reactive force field for hydrocarbons10.1021/jp004368u ↗
55. The role of grain boundaries in the corrosion process of Fe surface: insights from ReaxFF molecular dynamic simulations10.3390/met12050876 ↗
56. Texture analysis with MTEX – free and open source software toolbox10.4028/www.scientific.net/SSP.160.63 ↗
57. Thermomechanical processing induced lath martensite hierarchy and second phase coherency in a high strength low alloy steel10.1016/j.msea.2025.148450 ↗
58. The defining role of local shear on the development of as-rolled microstructure and crystallographic texture in steel10.1007/s11661-023-06981-6 ↗
59. Relating microstructures of hierarchical tertiary phases with corrosion performance in a super duplex stainless steel10.1016/j.matchar.2022.112426 ↗
60. Plastic deformation and corrosion in austenitic stainless steel: A novel approach through microtexture and infrared spectroscopy10.1016/j.corsci.2016.05.027 ↗
61. Statistical analysis of Tri-cresyl phosphate conversion on an iron oxide surface using reactive molecular dynamics simulations10.1021/acs.jpcc.9b02394 ↗
62. The effect of Fe-anion interactions on corrosion of ferrous surfaces by phosphonium ionic liquids10.1016/j.corsci.2023.111734 ↗
63. Thermal decomposition of tricresyl phosphate on ferrous surfaces10.1021/acs.jpcc.0c10789 ↗
64. Substituent effects on the thermal decomposition of phosphate esters on ferrous surfaces10.1021/acs.jpcc.9b11787 ↗
65. Mechanochemistry of phosphate esters confined between sliding iron surfaces10.1038/s42004-021-00615-x ↗
66. Direct microstructural observations and atomistic simulations on Hematite to Magnetite reduction10.1016/j.actamat.2025.121269 ↗
67. Fast parallel algorithms for short-range molecular dynamics10.1006/jcph.1995.1039 ↗
68. Visualization and analysis of atomistic simulation data with OVITO–the Open Visualization Tool10.1088/0965-0393/18/1/015012 ↗
69. Strain mode dependence of deformation texture developments: microstructural origin10.1007/s11661-010-0580-0 ↗
70. Humphreys · 2004
71. Thermo-Mechanical
72. Standard practice for calculation of corrosion rates and related information from electrochemical measurements
73. Schwartz · 2009
74. Three-dimensional characterization of grain boundaries in pure nickel by serial sectioning via mechanical polishing10.1107/S1600576715017616 ↗
75. On the alignment of 3D EBSD data collected by serial sectioning technique10.1016/j.matchar.2019.04.026 ↗
76. DREAM.3D: a digital representation environment for the analysis of microstructure in 3D10.1186/2193-9772-3-5 ↗
77. Grain boundary energy and relative ion damage: experimental observation and molecular dynamics simulation10.1080/09500839.2014.951706 ↗
78. Embedded-atom potential for Fe and its application to self-diffusion on Fe(100)10.1016/j.susc.2006.02.010 ↗
79. Theory of thermal grooving10.1063/1.1722742 ↗
80. The effect of thermal grooving on grain boundary motion10.1016/0001-6160(58)90020-8 ↗
81. Effect of misorientation angle and chromium concentration on grain boundary sensitisation in an austenitic stainless steel10.1016/j.matchar.2020.110343 ↗
82. Ternary Fe–Cu–Ni many-body potential to model reactor pressure vessel steels: First validation by simulated thermal annealing10.1080/14786430903299824 ↗
83. O. Engler, V. Randle, Introduction to Texture Analysis, 2nd ed., PUBLISHED BY IMPERIAL COLLEGE PRESS AND DISTRIBUTED BY WORLD SCIENTIFIC PUBLISHING CO., 2008. https://doi.org/10.1142/9781848161160_0001.10.1142/9781848161160_0001 ↗
84. Atomistic simulations of energies for arbitrary grain boundaries. Part II: Statistical analysis of energies for tilt and twist grain boundaries10.1016/j.commatsci.2019.03.010 ↗
85. Grain boundary energy function for α iron10.1016/j.mtla.2021.101186 ↗
86. Murr · 1975
87. Grain boundary segregation engineering in metallic alloys: a pathway to the design of interfaces10.1016/j.cossms.2014.06.002 ↗
88. Understanding of the interaction between crystallographic orientation and service environment on nonoriented silicon steel corrosion10.5006/4237 ↗
89. Microelectrode techniques for corrosion research of iron10.1016/j.electacta.2013.03.021 ↗
90. Correlation between grain orientation and surface dissolution of niobium10.1016/j.apsusc.2015.01.208 ↗
91. First-principles study of surface orientation dependent corrosion of BCC iron10.1016/j.corsci.2021.110029 ↗
92. Structural, electronic, and magnetic properties of bcc iron surfaces10.1016/j.susc.2006.09.013 ↗
93. Effects of Cu on the corrosion resistance of heat-treated weathering steel in a marine environment
94. Effect of Cu content on microstructure and mechanical properties for high-strength deposited metals strengthened by nano-precipitation10.3390/met12081360 ↗
95. Effect of Cu content on the precipitation behavior of Cu-rich and NiAl phases in steel10.1016/j.matchar.2022.111849 ↗
96. Consideration of particle-strengthening mechanism of copper-precipitation-strengthened steels by atom probe tomography analysis10.1016/j.msea.2011.12.056 ↗