Introduction of Heavy Micro‐Titanium‐Carbide Particles into Zn–Ni Coatings on Steel During In Situ Brush Electroplating

The heavy micro‐titanium‐carbide (TiC) particles are first introduced into brush‐electroplated Zn–Ni coating (TiC‐0 coating) by using some surfactants here. The effect of TiC concentration of brush‐electroplating solution on the properties of Zn–Ni–TiC coatings is investigated. It is found that the coating hardness and corrosion resistance are enhanced significantly due to the co‐deposition of TiC and an optimal coating with a thickness of 71 μm and adhesive strength of 37.2 MPa is obtained when TiC concentration was 40 (g L⁻¹) (TiC‐40 coating). The pencil hardness of TiC‐0 and TiC‐40 is 2 H and 5 H, respectively. The corrosion resistance time to hot NH₄NO₃ solution (or inferred neutral salt spray) of TiC‐0 and TiC‐40 are 40 and 240 min (or 321 and 1995 h), respectively. Many pores appear on the coating due to the incomplete overlap of many batch layers. The TiC content is the factor dominating the coating hardness and corrosion resistance by changing the structure, contact angle, and pore diameter of coating, thereby changing the linear polar resistance R_p from potentiodynamic polarization curves, charge‐transfer resistance R_ct or |Z|_{0.01 Hz}, or polarization resistance from electrochemical impedance spectroscopy. The content of Zn–Ni alloy is the factor dominating the adhesive strength of Zn–Ni–TiC coating.