Calciothermic Synthesis of Very Fine, Hydrogenated Ti and Ti–Nb Powder for Biomedical Applications

Due to their excellent biocompatibility, titanium and titanium–niobium alloys are especially interesting for biomedical applications. With regard to favorable near‐net shape production, Ti powder synthesis is the key hurdle. Extensive research has been in progress for alternative synthesis methods since decades. Herein, an efficient alternative method to the conventional powder production process to prepare spherical powders with very small sizes (<45 μm) for high‐strength materials is shown. Very fine, hydrogenated Ti and Ti–Nb alloy powders are stable in air and are synthesized by calciothermic reduction in hydrogen. The herein presented reduction using CaH₂ starts directly from the oxides instead of chlorides. Correlations of size and morphology of the as‐synthesized TiH₂ and (Ti,Nb)H₂ powders with the precursors (TiO₂, Nb₂O₅, and CaH₂) are illustrated and are used to tailor the desired powders.