Characterization of the Ag 43 Cu 37 Zn 20 alloy surface after potentiostatic polarization using LDI-TOF mass spectrometry
Source abstract
Abstract
Abstract This work is the first to demonstrate the possibilities of direct analysis of the corrosion film formed on Ag 43 Cu 37 Zn 20 alloy using laser desorption/ionization (LDI) on a commercial matrix-assisted LDI time of flight mass spectrometry (MS) instrument. In the LDI mass spectra measured from the water solution of the corrosion film, the ion species Zn + , Zn(H 2 O) + , AgH + , Cu 2 H + , Cu 2 O(OH) + , Cu 3 O(OH) + (high intensity), and Cu(OH)(H 2 O) + , ZnCl(OH)(H 2 O) + , AgCl + , CuCl + (low intensity) were identified. The LDI mass spectra of the propan-2-ol solution of the corrosion film contains the ions Zn 5 Cl(OH) 3 (H 2 O) 11 + , Zn 5 Cl 2 (OH) 8 (H 2 O) 6 + , and Zn 5 Cl 2 (OH)(H 2 O) 14 + . Mass spectra were observed at laser energies in the range of 1340–1860 arbitrary units in positive ion mode. Previously, Raman spectra and X-ray diffraction (XRD) analysis of the same anodic film have shown similar results as LDI MS – that the anodic film contains the mixture of Ag, Cu 2 O, CuCl, Zn 5 Cl 2 (OH) 8 ·H 2 O, and β-Zn(OH)Cl. LDI MS could be a complementary method for XRD and Raman, as demonstrated in this investigation. The LDI MS method greatly reduces the analysis time and amount of the sample compared to traditional methods. For this reason, the LDI MS method can be a useful tool for the fast qualitative screening of corrosion films.
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Research context
OpenAlex topics: Mass Spectrometry Techniques and Applications · Ion-surface interactions and analysis · Cultural Heritage Materials Analysis
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Affiliations
University of Belgrade , Vinča Institute of Nuclear Sciences , PO Box 522, 11001 Belgrade , Serbia
University of Belgrade , Innovation Centre of TMF Belgrade , Karnegijeva 4, 11120 Belgrade , Serbia
Mining and Metallurgy Institute Bor, Zeleni bulevar 35 , 19210 Bor , Serbia
University of Belgrade, The Faculty of Technology and Metallurgy, Karnegijeva 4 , 11120 Belgrade , Serbia
References (37)
Show source-provided references
1. Amato F, Panyala NR, Vašina P, Havel J. Laser desorption ionisation quadrupole ion trap time-of-flight mass spectrometry of titanium-carbon thin films. Rapid Commun Mass Spectrom 2013; 27: 1196–1202.10.1002/rcm.6564 ↗
2. Blagojevic V, Samad SN, Banu L, Thomas MC, Blanksby SJ, Bohme DK. Mass spectrometric study of the dissociation of Group XI metal complexes with fatty acids and glycerolipids: Ag2H+ and Cu2H+ ion formation in the presence of a double bond. Int J Mass Spectrom 2011; 299: 125–130.10.1016/j.ijms.2010.09.031 ↗
3. Buckner S, Gord J, Freiser B. Gas phase studies of Zn2, Ag3, and Ag5. J Chem Phys 1988; 88: 3678–3682.10.1063/1.453867 ↗
4. Crousier J, Pardessus L, Crousier JP. Voltammetry study of copper in chloride solution. Electrochim Acta 1988; 33: 1039–1042.10.1016/0013-4686(88)80192-0 ↗
5. De Hoffmann E, Stroobant V. Mass spectrometry principles and applications, 3rd ed., Chichester, UK: John Wiley & Sons Ltd., 2007.
6. De la Fuente D, Alcántara J, Chico B, Díaz I, Jiménez JA, Morcillo M. Characterisation of rust surfaces formed on mild steel exposed to marine atmospheres using XRD and SEM/micro-Raman techniques. Corros Sci 2016; 110: 253–264.10.1016/j.corsci.2016.04.034 ↗
7. Dimitrijević SP, Lazarević ZŽ, Rajčić-Vujasinović M, Dimitrijević SB, Petrović M, Gilić M, Jokić BM. Raman spectroscopy study of anodic film on Ag43Cu37Zn20 alloy. Optoelectron Adv Mater Rapid Commun 2016; 10: 777–780.
8. Egerton RF. Physical principles of electron microscopy: an introduction to TEM, SEM, and AEM. New York, USA: Springer, Science+Business Media Inc., 2005.10.1007/b136495 ↗
9. Gord JR, Bemish RJ, Freiser BS. Collision-induced dissociation of positive and negative copper oxide cluster ions generated by direct laser desorption/ionization of copper oxide. Int J Mass Spectrom Ion Proc 1990; 102: 115–132.10.1016/0168-1176(90)80055-8 ↗
10. Hidaka H, Hanyu N, Sugano M, Kawasaki K, Yamauchi K. Analysis of human serum lipoprotein lipid composition using MALDI-TOF mass spectrometry. Ann Clin Lab Sci 2007; 37: 213–221.
11. Houska J, Alberti M, Havel J. Laser ablation synthesis of phosphorus sulphides, selenides and ternary PpSqSer clusters from various precursors. Rapid Commun Mass Spectrom 2008; 22: 417–423.10.1002/rcm.3375 ↗
12. Houska J, Pena-Mendez EM, Kolar J, Frumar M, Wagner T, Havel J. Laser ablation of AgSbS2 and cluster analysis by time-of-flight mass spectrometry. Rapid Commun Mass Spectrom 2009; 23: 1715–1718.10.1002/rcm.4048 ↗
13. Huapeng C, Jing L, Duan W, Ping C. Dimetal hydride generated from dimetalated glycine: formation mechanism and electronic structure. Intern J Mass Spectrom 2014; 363: 32–39.10.1016/j.ijms.2014.02.014 ↗
14. Karas M, Hillenkamp F. Laser desorption ionization of proteins with molecular masses exceeding 10,000 daltons. Anal Chem 1988; 60: 2299–2301.10.1021/ac00171a028 ↗
15. Kéki S, Szilágyi SL, Török J, Deák G, Zsuga M. Bimetallic silver-gold clusters by matrix-assisted laser desorption/ionization. J Phys Chem B 2003; 107: 4818–4825.10.1021/jp0274334 ↗
16. Khairallah GN, O’Hair AJ. Gas phase synthesis and reactivity of Agn+ and Agn-1H+ cluster cations, Dalton Trans 2005; 16: 2702–2712.10.1039/b505645b ↗
17. Kussmann M, Nordhoff E, Rahbek-Nielsen H, Rossel S. Matrix-assisted laser desorption/ionization mass spectrometry sample preparation techniques designed for various peptide and protein analytes. J Mass Spectrom 1997; 32: 593–601.10.1002/(SICI)1096-9888(199706)32:6<593::AID-JMS511>3.0.CO;2-D ↗
18. Ma AL, Jiang SL, Zheng YG, Ke W. Corrosion product film formed on the 90/10 copper-nickel tube in natural seawater: composition/structure and formation mechanism. Corros Sci 2015; 91: 245–261.10.1016/j.corsci.2014.11.028 ↗
19. Musaev OR, Driver MS, Sutter EA, Caruso AN, Wrobel JM, Kruger MB. Influence of the liquid environment on the products formed from the laser ablation of tin. Appl Phys A 2013; 113: 355–359.10.1007/s00339-013-7635-1 ↗
20. Pangavhane SD, Houska J, Wágner T, Pavlista M, Janca J, Havel J. Laser ablation of ternary As-S-Se glasses and time-of-flight mass spectrometric study. Rapid Commun Mass Spectrom 2010a; 24: 95–102.10.1002/rcm.4362 ↗
21. Pangavhane SD, Nemec P, Wagner T, Janca J, Havel J. Laser desorption ionization time-of-flight mass spectrometric study of binary As-Se glasses. Rapid Commun Mass Spectrom 2010b; 24: 2000–2008.10.1002/rcm.4607 ↗
22. Pangavhane SD, Hebedova L, Alberti M, Havel J. Laser ablation synthesis of new phosphorus nitride clusters from alpha-P3N5 via laser desorption ionization and matrix-assisted laser desorption ionization time-of-flight mass spectrometry. Rapid Commun Mass Spectrom 2011; 25: 917–924.10.1002/rcm.4937 ↗
23. Panyala NR, Prysiazhnyi V, Slavicek P, Cernak M, Havel J. Formation of aluminium, aluminium nitride and nitrogen clusters via laser ablation of nano aluminium nitride. Laser desorption ionisation and matrix-assisted laser desorption ionisation time-of-flight mass spectrometry. Rapid Commun Mass Spectrom 2011; 25: 1687–1693.10.1002/rcm.5030 ↗
24. Panyala NR, Peña-Méndez EM, Havel J. Laser ablation synthesis of new gold phosphides using red phosphorus and nanogold as precursors. Laser desorption ionization time-of-flight mass spectrometry. Rapid Commun Mass Spectrom 2012; 26: 1100–1108.10.1002/rcm.6207 ↗
25. Perez F, Castaneda S. TG-mass spectrometry studies in coating design for supercritical steam turbines. Mater Corros 2008; 59: 409–413.10.1002/maco.200804123 ↗
26. Petkovic M, Schiller J, Mueller M, Benard S, Reichl S, Arnold K, Arnhold J. Detection of individual phospholipids in lipid mixtures by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry: phosphatidylcholine prevents the detection of further species. Anal Biochem 2001; 289: 202–216.10.1006/abio.2000.4926 ↗
27. Picca RA, Calvano CD, Cioffi N, Palmisano F. Mechanisms of nanophase-induced desorption in LDI-MS. A short review. Nanomaterials 2017; 7: 75–95.10.3390/nano7040075 ↗
28. Ramirez-Galicia G, Pena-Mendez EM, Pangavhane SD, Alberti M, Havel J. Mass spectrometry and ab initio calculation of AsSn+ (n=1–7) ion structures. Polyhedron 2010; 29: 1567–1570.10.1016/j.poly.2010.02.012 ↗
29. Rashidzadeh H, Guo B. Generation of large gas-phase silver cluster ions by laser desorption ionization of silver-containing salts. Chem Phys Lett 1999; 310: 466–470.10.1016/S0009-2614(99)00819-2 ↗
30. Sauer S. The essence of DNA sample preparation for MALDI mass spectrometry. J Biochem Biophys Methods 2007; 70: 311–318.10.1016/j.jbbm.2006.10.007 ↗
31. Schiller J, Suß R, Arnhold J, Fuchs B, Leßig J, Muller M, Petkovic M, Spalteholz H, Zschornig O, Arnold K. Matrix-assisted laser desorption and ionization time-of-flight (MALDI-TOF) mass spectrometry in lipid and phospholipid research. Prog Lipid Res 2004; 43: 449–488.10.1016/j.plipres.2004.08.001 ↗
32. Scott McIndoe J. Laser synthesis of transition metal clusters. Trans Met Chem 2003; 28: 122–131.10.1023/A:1022515104991 ↗
33. Tanaka K, Waki H, Ido Y, Akita S, Yoshida Y, Yoshida T, Matsuo T. Protein and polymer analyses up to m/z 100 000 by laser ionisation time-of-flight mass spectrometry. Rapid Commun Mass Spectrom 1988; 2: 151–153.10.1002/rcm.1290020802 ↗
34. Wang J, Wang J. Influence of ethanolamine on corrosion of alloy 690 in simulated secondary water. J Mater Sci Technol 2015; 31: 1039–1046.10.1016/j.jmst.2014.09.022 ↗
35. Zenobi R, Knochenmuss R. Ion formation in MALDI mass spectrometry. Mass Spectrom Rev 1998; 17: 337–366.10.1002/(SICI)1098-2787(1998)17:5<337::AID-MAS2>3.0.CO;2-S ↗
36. Zhang J, Frankevich V, Knochenmuss R, Friess SD, Zenobi R. Reduction of Cu(II) in matrix-assisted laser desorption/ionization mass spectrometry. J Am Soc Mass Spectrom 2003; 14: 42–50.10.1016/S1044-0305(02)00807-3 ↗
37. Zhou P, Hutchison MJ, Erning JW, Scully JR, Ogle K. An in situ kinetic study of brass dezincification and corrosion. Electrochim Acta 2017; 229: 141–154.10.1016/j.electacta.2017.01.078 ↗