Quantitative Analysis of Hydrogen‐Assisted Microcracking in Duplex Stainless Steel through X‐Ray Refraction 3D Imaging

While the problem of the identification of mechanisms of hydrogen‐assisted damage has and is being thoroughly studied, the quantitative analysis of such damage still lacks suitable tools. In fact, while, for instance, electron microscopy yields excellent characterization, the quantitative analysis of damage requires at the same time large field‐of‐views and high spatial resolution. Synchrotron X‐ray refraction techniques do possess both features. Herein, it is shown how synchrotron X‐ray refraction computed tomography (SXRCT) can quantify damage induced by hydrogen embrittlement in a lean duplex steel, yielding results that overperform even those achievable by synchrotron X‐ray absorption computed tomography. As already reported in the literature, but this time using a nondestructive technique, it is shown that the hydrogen charge does not penetrate to the center of tensile specimens. By the comparison between virgin and hydrogen‐charged specimens, it is deduced that cracks in the specimen bulk are due to the rolling process rather than hydrogen‐assisted. It is shown that (micro)cracks propagate from the surface of tensile specimens to the interior with increasing applied strain, and it is deduced that a significant crack propagation can only be observed short before rupture.