Improved corrosion inhibition by heterocyclic compounds on mild steel in acid medium
Source abstract
Abstract
Abstract A detailed comparative study on inhibitive behaviour against corrosion of mild steel in 1N H 2 SO 4 IN HCl for the Schiff bases 2,6-diphenyl-3-methyl azinan-4-one (D3MA) (S1), 2,6-diphenyl-3-methyl azinan-4-one semicarbazone (D3MAS) (S2), 2,6-diphenyl azinan-4-one (DA) (S3) and 2,6-diphenylazinan-4-one semicarbazone (DAS) (S4) was investigated using gravimetric and potentiodynamic polarisation methods. The thermodynamic parameters for the mild steel corrosion and the synergistic behaviour of the inhibitors in the presence of anions and cations were determined and discussed. It was found that the adsorption of the inhibitors on the mild steel surface obeyed Langmuir adsorption isotherm. Electro chemical studies revealed that all the four inhibitors are of mixed type. We proved that the semicarbazones (Schiff bases S2b and S4) with additional O and N are more effective corrosion inhibitors than their parent keto-amines. As a whole from all the proposed studies it is proved that the explored Schiff’s bases work as a very efficient corrosion inhibitor for mild steel in both the acidic medium.
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Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Concrete Corrosion and Durability · Inorganic and Organometallic Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry , PSG College of Arts & Science , Coimbatore , Tamil Nadu , India
Department of Chemistry , Dr. Mahalingam College of Engineering and Technology , Pollachi 64200 , Tamil nadu , India
Department of Chemistry , Gobi Arts & Science College (Autonomous) , Gobichettipalayam , Tamil Nadu , India
Anticancer Bioscience, Tianfu International Biotown , Chengdu , China
Environmental Engineering and Management Research Group, Ton Duc Thang University , Ho Chi Minh City , Vietnam
Faculty of Environment and Labour Safety, Ton Duc Thang University , Ho Chi Minh City , Vietnam
References (50)
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