Preparation of Porous Silver Nanowires‐Melamine Formaldehyde Hybrid Composite Materials and Their Electromagnetic Shielding and Flame‐Retardant Properties

Along with the booming development of communication technology and electronic equipment, higher requirements of flame‐retardant and EMI shielding performances for electromagnetic interference (EMI) shielding materials are put forward. Herein, the ultralight and porous silver nanowires (AgNWs)‐melamine formaldehyde (MF) hybrid composite with unique micro‐/nanostructure is developed by a facile dip‐coating method, which uses the AgNWs as 1D conductive coating and MF foam (MF foam) as 3D skeleton template. Benefiting from the unique porous micro‐/nanostructure, the resultant hybrid composite displays low density, excellent EMI shielding performances, and superior flame‐retardant property. The EMI shielding effectiveness (SE) and specific EMI SE (SSEt) of the hybrid composite in X‐band (8.2–12.4 GHz) can be up to 77 dB and 26971.4 dB cm⁻² g⁻¹, respectively. At the same time, the hybrid composite also passes the vertical burning test and shows an increased LOI value of 40.6%. The combination of flame‐retardant and EMI shielding performances for EMI shielding materials makes the AgNWs‐MF hybrid composite great application potential in civil and military fields. This work provides a new guide for the design of multifunctional high‐performance EMI shielding materials.