Flexible and Dual‐Sided Available Colored Films for Efficient Daytime Radiative Cooling

Passive daytime radiative cooling (PDRC) is a promising strategy to realize surface cooling of objects without any external energy consumption. While such materials typically exhibit dazzling white appearances, developing pleasingly looking colored radiative cooling materials is greatly significant but remains an arduous challenge. Herein, self‐standing, flexible colored films available on both sides are prepared by using a facile and scalable strategy. The films are asymmetrically designed. One side is SiO₂‐filled porous structure with highly reflective pigment distributed that can selectively reflect solar light to generate specific color, and the other side is hierarchically porous three‐phase composite with less SiO₂, which maximizes the solar reflection. The breathable film achieves a relatively high near infrared reflectance on the colored side (up to 89%), and a broadband solar reflectance on the reverse side. Moreover, both sides exhibit extremely high mid‐infrared emissivity (98%) allowing significant radiative heat loss. With the diverse but efficient reflectance and emittance, different sides of three colored films yield temperature drops ranging from 2.0 to 11.1 °C during daytime. Building energy simulation indicates that 655 MJ m⁻² energy can be saved over the whole summer if the dual‐sided available colored film is deployed in China.