The Effect of Chemistry and 3D Microstructural Architecture on Corrosion of Biodegradable Mg–Ca–Zn Alloys

The development of biodegradable Mg–Ca–Zn alloys strongly relies on the understanding of the varying 3D microstructural architectures by means of high‐density‐resolution imaging, such as synchrotron radiation–based X‐ray microtomography (SR‐μCT). The development of useful strategies to control the degradation process, including the design of appropriate 3D microstructures, focusing on the type, fraction, morphology, distribution, connectivity, and interfaces of different phases, depends on a comprehensive understanding of the underlying corrosion processes. SR‐μCT enables the nondestructive analysis of the same microstructure within a volume exposed to different immersion times in artificial physiological solutions, e.g., Hanks’ balanced salt solution without glucose (HBSS). In this work, quantitative 3D imaging via SR‐μCT demonstrates the formation of a continuous 3D network of secondary phases for low‐alloyed Mg–Ca–Zn. Furthermore, a change in the corrosion mechanism from very localized to uniform heterogeneous corrosion processes is observed. This mechanistic change is associated not exclusively with the electrochemical activity of the primary α‐Mg_SS and the secondary (Mg,Zn)₂Ca and Mg–Ca–Zn phases, but also with their volume fraction, distribution, 3D morphology, connectivity, and the formation of corrosion product layers.