Phase Formation and Densification Peculiarities of Hf–C–N Solid Solution Ceramics during Reactive Spark Plasma Sintering
Source abstract
Abstract
Herein, phase formation and sintering of hafnium carbonitride ceramics from a 4HfC–3HfN powder mixture using reactive spark plasma sintering are studied. X‐ray diffraction (XRD) data show that the mutual heterodiffusion of carbon C and nitrogen N increases with sintering temperature within the studied temperature range 1500–2100 °C. 4HfC–3HfN powder sintering at 1900 °C for 5 min under 60 MPa pressure yields HfCxN1−x solid solution ceramics. The ceramic sample prepared under optimal conditions (2100 °C, 5 min, 60 MPa) is characterized by an average grain size of 10 μm, microhardness of 19.6–22.5 GPa, and relative density above ≈97%.
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Research context
OpenAlex topics: Advanced ceramic materials synthesis · Advanced materials and composites · Metal and Thin Film Mechanics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Natural Sciences Far Eastern Federal University Sukhanova Street 8 Vladivostok 690950 Russia
Institute for Automation and Control Processes Far Eastern Branch Russian Academy of Sciences Radio Street 5 Vladivostok 690041 Russia
School of Engineering Far Eastern Federal University Sukhanova Street 8 Vladivostok 690950 Russia
Institute of Chemistry Far-Eastern Branch Russian Academy of Sciences 100-let Vladivostoku Avenue 159 Vladivostok 690022 Russia
Funding
Russian Science Foundation
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