journal article·2023-09Open access

Flash and Breakdown: Thermal Runaway and Dielectric Breakdown as Competing Mechanisms During Flash Sintering of Barium Titanate

Daniil Lewin, Ivo Michiels, Sobhan Mohammadi Fathabad, Eva Kröll, Karl-Heinz Menze, Doru C. Lupascu

Advanced Engineering Materials· Volume 25· Issue 18

Abstract

Herein, hot‐spot generation in bulk barium titanate samples is investigated during controlled current ramping at various rates using in situ dilatometry. The incubation of the flash event is separated from dielectric breakdown at high current densities, which has previously been attributed to cause flash incubation in barium titanate. The lower boundary of the onset temperature of the flash event in barium titanate is investigated through conventional flash experiments at high electric fields. Despite incubating through thermal runaway, the lower boundary does not coincide with the Debye temperature of barium titanate.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Electronic and Structural Properties of Oxides · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute for Materials Science and Center for Nanointegration Duisburg-Essen (CENIDE) University of Duisburg-Essen Universitätsstrasse 15 45141 Essen Germany

Funding

Deutsche Forschungsgemeinschaft

References (30)

Show source-provided references
1. 10.1016/j.scriptamat.2020.04.02210.1016/j.scriptamat.2020.04.022 ↗
2. 10.1016/j.jeurceramsoc.2018.08.04810.1016/j.jeurceramsoc.2018.08.048 ↗
3. 10.1063/1.296370110.1063/1.2963701 ↗
4. 10.1126/science.aaz768110.1126/science.aaz7681 ↗
5. 10.1039/D2MH00177B10.1039/D2MH00177B ↗
6. Trombin F. · Am. Ceram. Soc. Bull. · 2014 · 93 · 32
7. 10.1111/jace.1784710.1111/jace.17847 ↗
8. 10.1111/jace.1493810.1111/jace.14938 ↗
9. 10.1016/j.jeurceramsoc.2014.04.04110.1016/j.jeurceramsoc.2014.04.041 ↗
10. 10.1111/j.1551-2916.2010.04089.x10.1111/j.1551-2916.2010.04089.x ↗
11. 10.1016/j.jeurceramsoc.2022.05.05310.1016/j.jeurceramsoc.2022.05.053 ↗
12. 10.2109/jcersj2.123.46510.2109/jcersj2.123.465 ↗
13. 10.1016/j.jeurceramsoc.2022.11.01610.1016/j.jeurceramsoc.2022.11.016 ↗
14. 10.1016/j.jeurceramsoc.2018.04.00310.1016/j.jeurceramsoc.2018.04.003 ↗
15. 10.1111/jace.1603710.1111/jace.16037 ↗
16. 10.1111/jace.1703710.1111/jace.17037 ↗
17. 10.1016/j.scriptamat.2018.11.00910.1016/j.scriptamat.2018.11.009 ↗
18. 10.1016/j.scriptamat.2019.05.03010.1016/j.scriptamat.2019.05.030 ↗
19. 10.2109/jcersj2.1525910.2109/jcersj2.15259 ↗
20. 10.1103/PhysRevB.83.05411210.1103/PhysRevB.83.054112 ↗
21. 10.1016/j.commatsci.2010.04.02610.1016/j.commatsci.2010.04.026 ↗
22. 10.1016/j.ssi.2018.03.01410.1016/j.ssi.2018.03.014 ↗
23. 10.1016/j.scriptamat.2020.01.00710.1016/j.scriptamat.2020.01.007 ↗
24. 10.1049/hve2.1208010.1049/hve2.12080 ↗
25. 10.1016/j.actamat.2018.12.00710.1016/j.actamat.2018.12.007 ↗
26. 10.1016/j.ceramint.2020.02.05510.1016/j.ceramint.2020.02.055 ↗
27. 10.1016/j.scriptamat.2020.05.00510.1016/j.scriptamat.2020.05.005 ↗
28. 10.1002/adfm.20150082710.1002/adfm.201500827 ↗
29. 10.1016/S0167-2738(99)00012-010.1016/S0167-2738(99)00012-0 ↗
30. 10.3390/ma1411286410.3390/ma14112864 ↗