Highly Oriented Zirconium Nitride and Oxynitride Coatings Deposited via High‐Power Impulse Magnetron Sputtering: Crystal‐Facet‐Driven Corrosion Behavior in Domestic Wastewater
Source abstract
Abstract
Herein, highly crystalline ZrxNy and ZrxNyOz coatings are achieved by the deposition via high‐power impulse magnetron sputtering. Various N2 and N2/O2 gas mixtures with argon are investigated. The chemical composition and, as a result, mechanical properties of the deposited layer can be tailored along with morphological and crystallographic structural changes. The corrosion resistance behavior is studied by potentiodynamic measurements and electrochemical impedance spectroscopy in a sample of synthetic wastewater designed to imitate real‐life domestic wastewater. The corrosion current density of the ZrxNyOz coating is in the range of 33–70 μA cm−2, whereas for the zirconium nitride layers, values below 1.0 μA cm−2 are achieved. The highest corrosion resistance of 64 nm year−1 is observed for the ZrxNy coating deposited with 1.00% N2 content in the gas mixture with a corrosion potential of −0.41 V Ag/AgCl.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Metal and Thin Film Mechanics · Semiconductor materials and devices · MXene and MAX Phase Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Faculty of Chemistry Department of Energy Conversion and Storage Gdańsk University of Technology Narutowicza 11/12 80-233 Gdańsk Poland
Faculty of Electronics, Telecommunications and Informatics Department of Metrology and Optoelectronics Gdańsk University of Technology Narutowicza 11/12 80-233 Gdańsk Poland
Institute of Physics University of South Bohemia Branisovska 1760 370 05 Ceske Budejovice Czech Republic
Faculty of Applied Physics and Mathematics Advanced Materials Center and Institute of Nanotechnology and Materials Engineering Gdańsk University of Technology Narutowicza 11/12 80-233 Gdańsk Poland
Faculty of Chemistry Department of Electrochemistry Corrosion and Materials Engineering Gdańsk University of Technology Narutowicza 11/12 80-233 Gdańsk Poland
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