Enhanced Mechanical Energy Harvesting in Triboelectric Nanogenerator by the Reinforcement of Polypyrrole‐Decorated rGO Sheets in PDMS

Energy harvesting triboelectric nanogenerators (TENGs) to scavenge unused mechanical energy have received significant attention in this decade. Herein, the development of reduced graphene oxide (rGO):polypyrrole (PPy) hybrid‐modified polydimethylsiloxane (PDMS) as TENG for various device applications is reported. The bulk of PDMS is altered by different fillers such as rGO, PPy, and the binary hybrids of rGO and PPy with varying weight ratios. Among various PDMS composites, 1 wt% of 1:8 rGO:PPy–PDMS composite exhibits higher TENG responses than other PDMS composite. The superior TENG performances of 1 wt% 1:8 rGO:PPy–PDMS composite are attributed to the formation of intensified negative charges inside the PDMS matrix. This charge intensification in the composite is due to various mechanisms, including the charge trapping ability of rGO:PPy filler, microcapacitor formation by introducing hybrid filler in the system with proper conducting networks, and the electron‐donating nature of PPy conducting polymer. A 3D stacked device proposed using 1 wt% 1:8 rGO:PPy–PDMS composite delivered a short‐circuit current of 16 μA and an open‐circuit potential of 60 V by simple palm pressing. Also, the ability of the stacked device for charging/powering portable devices and light‐emitting diodes is demonstrated.