In Situ Observation of Various Phase Transformation Paths in Nb‐Rich TiAl Alloys during Quenching with Different Rates

Abstract In recent years intermetallic γ‐TiAl based alloys with additional amounts of the ternary β phase have attracted attention due to their improved hot workability. Depending on alloy composition and heat treatment the ternary β phase can transform to different ternary phases at lower temperatures. A few of them are assumed to be detrimental to ductility. However, the current phase diagrams of these multiphase materials are often quite uncertain. Thus, the possible transformations of third phases in the temperature range between 700 and 1 100 °C are studied by means of in situ high‐energy X‐ray diffraction (HEXRD). Depending on quenching rate reversible transformations of β_o to different ω related phases are observed, indicating a stepwise diffusion controlled transformation mechanism of B2‐ordered β_o to B8₂‐ordered ω_o. Apparently, the addition of Mo can hinder this transformation.