DataVXAdvanced Energy MaterialsPaper
journal article·2025-03Open access

Photoelectrochemical Synthesis of Adipic Acid by Selective Oxidation of Cyclohexanone (Adv. Energy Mater. 11/2025)

Shanshan Zhang, Lan Luo, Jiangrong Yang, Wangsong Chen, Yucong Miao, Ruikang Zhang, Zhenhua Li, Rengui Li, Mingfei Shao, Xue Duan

Advanced Energy Materials· Volume 15· Issue 11
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Source abstract

Abstract

Photoelectrochemical Syntheses In article number 2405052, Ruikang Zhang, Zhenhua Li, Mingfei Shao, and co-workers first reported a photoelectrochemical strategy to achieve the selective oxidation of cyclohexanone to adipic acid using a cooperative Ni(OH)2/TiO2 photoanode with H2O as oxygen source. The new Ni2+δ─OH* reactive center was in situ generated on a Ni(OH)2/TiO2 photoanode under illumination, which significantly facilitates the activation of Cα─H and the subsequent C─C cleavage to produce adipic acid.
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Research context

OpenAlex topics: Water Quality Monitoring and Analysis · Advanced Chemical Sensor Technologies

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Affiliations

State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology Beijing 100029 China

Tianjin Key Laboratory of Brine Chemical Engineering and Resource Eco‐utilization College of Chemical Engineering and Materials Science Tianjin University of Science and Technology Tianjin 300457 China

College of Chemistry and Materials Science Hebei Normal University Shijiazhuang Hebei 050024 China

Quzhou Institute for Innovation in Resource Chemical Engineering Quzhou 324000 China

State Key Laboratory of Catalysis Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116023 China

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