journal article·2023-08Open access

The Emergence of 2D Building Units in Metal‐Organic Frameworks for Photocatalytic Hydrogen Evolution: A Case Study with COK‐47 (Adv. Energy Mater. 31/2023)

Pablo Ayala, Shaghayegh Naghdi, Sreejith P. Nandan, Stephen Nagaraju Myakala, Jakob Rath, Hikaru Saito, Patrick Guggenberger, Lakhanlal Lakhanlal, Freddy Kleitz, Maytal Caspary Toroker, Alexey Cherevan, Dominik Eder

Advanced Energy Materials· Volume 13· Issue 31

Abstract

Hydrogen Evolution Reaction In article number 2300961, Dominik Eder and co-workers test a visible light responsive titanium-based metal-organic framework (MOF) comprised of 2D secondary building units for the hydrogen evolution reaction. It ranks amongst the highest performing MOFs for this challenging conversion. Upon photoexcitation, this unique structure enables efficient charge separation and extraction, displaying a ligand to metal charge transfer mechanism and boosting H2 formation.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Advanced Nanomaterials in Catalysis · Advanced Photocatalysis Techniques

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Affiliations

Institute of Materials Chemistry TU Wien Vienna 1060 Austria

Institute of Materials Chemistry and Engineering Kyushu University Fukuoka 816–8580 Japan

Department of Inorganic Chemistry – Functional Materials Faculty of Chemistry University of Vienna Vienna 1090 Austria

Vienna Doctoral School in Chemistry (DoSChem) University of Vienna Vienna 1090 Austria

Department of Materials Science and Engineering Technion – Israel Institute of Technology Haifa 3200003 Israel

The Nancy and Stephen Grand Technion Energy Program Technion – Israel Institute of Technology Haifa 3200003 Israel

References

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