journal article·2003-05-01

A Mechanistic Model for Carbon Dioxide Corrosion of Mild Steel in the Presence of Protective Iron Carbonate Films—Part 1: Theory and Verification

M. Nordsveen, S. Nešić, R. Nyborg, A. Stangeland

Corrosion· Volume 59· Issue 5
Publisher page

Abstract

A mechanistic model of uniform carbon dioxide (CO2) corrosion is presented that covers the following: electrochemical reactions at the steel surface, diffusion of species between the metal surface and the bulk including diffusion through porous surface films, migration due to establishment of potential gradients, and homogenous chemical reactions including precipitation of surface films. The model can predict the corrosion rate as well as the concentration and flux profiles for all species involved. Comparisons with laboratory experiments have revealed the strengths of the model such as its ability to assist in understanding complex processes taking place during corrosion in the presence of surface films.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Concrete Corrosion and Durability · CO2 Sequestration and Geologic Interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

*Institute for Energy Technology, N-2027 Kjeller, Norway.

**Institute for Energy Technology, N-2027 Kjeller, Norway. Present address: Institute for Corrosion and Multiphase Flow Technology, Chemical Engineering Department, Ohio University, 340 ½ W. State St., Stocker Center, Athens, OH 45701.

***Institute for Energy Technology, N-2027 Kjeller, Norway.

****Institute for Energy Technology, N-2027 Kjeller, Norway.

References (56)

Show source-provided references
1. de Waard · Corrosion · 1975 · 31 · 13110.5006/0010-9312-31.5.177 ↗
2. de Waard · Corrosion · 1991 · 47 · 97610.5006/1.3585212 ↗
3. Influence of Liquid Flow Velocity on CO2 Corrosion: A Semi-Empirical Model
4. Basics of the Prediction of the Risks of CO2 Corrosion in Oil and Gas Wells
5. Crolet · SPE Prod. Eng. · 1991 · 6 · 44910.2118/20835-PA ↗
6. Combining Research and Field Data for Corrosion Rate Prediction
7. CO2 Corrosion Model for Carbon Steel Including a Wall Shear Stress Model for Multiphase Flow and Limits for Production Rate to Avoid Mesa Attack
8. “CO2 Corrosion Rate Calculation Model,” NORSOK Standard no. M-506, Norwegian Technology Standards Institution, http://www.nts.no/norsok, June 1998.
9. A.J. McMahon, D.M.E. Paisley, “Corrosion Prediction Modelling—A Guide to the Use of Corrosion Prediction Models for Risk Assessment in Oil and Gas Production and Transportation Facilities,” Report no. ESR.96.ER.066 (Sunbury: BP International, 1997).
10. Computer Modeling to Predict Corrosion Rates in Gas Condensate Wells Containing CO2
11. Prediction of Corrosivity of CO2/H2S Production Environments
12. SweetCor: An Information System for the Analysis of Corrosion of Steels by Water and Carbon Dioxide
13. Model for Sweet Corrosion in Horizontal Multiphase Slug Flow
14. Development of a Mechanistic Model for Predicting Corrosion Rate in Multiphase Oil/Water/Gas Flows
15. Mechanistic Models for the Prediction of CO2 Corrosion Rates under MultiPhase Flow Conditions
16. Simulation of CO2/H2S Corrosion Using Thermodynamic and Electrochemical Models
17. CO2 Corrosion Prediction in Pipe Flow Under FeCO3 Scale-Forming Conditions
18. Deterministic Modeling of Corrosion in Downhole Environments
19. Mechanistic Modeling of Mass Transfer in the Laminar Sublayer in Downhole Systems
20. Nĕsić · Corros. Rev. · 1997 · 15 · 21110.1515/CORRREV.1997.15.1-2.211 ↗
21. Overview of CO2 Corrosion Models for Wells and Pipelines
22. Mechanism of Protective Film Formation During CO2 Corrosion of Carbon Steel
23. Initiation and Growth of Mesa Corrosion Attack During CO2 Corrosion of Carbon Steel
24. Mesa Corrosion Attack in Carbon Steel and 0.5% Chromium Steel
25. Mechanisms of Carbon Steel Corrosion in Brines Containing Dissolved Carbon Dioxide
26. Effect of Flow on CO2 Corrosion Rates in Real and Synthetic Formation Waters
27. Effect of pH and Temperature on the Mechanism of Carbon Steel Corrosion by Aqueous Carbon Dioxide
28. Delahay · J. Am. Chem. Soc. · 1952 · 74 · 3,49710.1021/ja01134a013 ↗
29. Nĕsić · Corrosion · 1996 · 52 · 28010.5006/1.3293640 ↗
30. Iron and its Electrochemistry in an Active State10.1007/978-1-4684-8667-4_2 ↗
31. Anodic Dissolution of Iron Group Metals
32. Bockris · Electrochim. Acta · 1961 · 4 · 32510.1016/0013-4686(61)80026-1 ↗
33. Schmitt · Werkst. Korros. · 1977 · 28 · 81610.1002/maco.19770281203 ↗
34. Electrochemical Properties of Iron Dissolution in the Presence of CO2—Basics Revisited
35. Davies · Corrosion · 1980 · 36 · 38510.5006/0010-9312-36.8.416 ↗
36. Fundamental Studies Aimed at Improving Models for Prediction of CO2 Corrosion
37. Newman · 1991
38. Simplified Calculation of CaCO3 Saturation at High Temperatures and Pressures in Brine Solutions
39. IUPAC
40. Kharaka · 1989
41. Palmer · Chem. Rev. · 1983 · 83 · 65110.1021/cr00058a004 ↗
42. Comprehensive Chemical Kinetics · 1972 · 283
43. Vetter · 1961 · 40610.1007/978-3-642-86547-3 ↗
44. Ferrous Carbonate Precipitation Kinetics and Its Impact on CO2 Corrosion
45. The Formation of Protective FeCO3 Corrosion Product Layers in CO2 Corrosion
46. Sundman · 1997
47. Mullin · 1993
48. Perry · 1984
49. A Kinetic Model for Calculating Concentration Profiles and Fluxes of CO2-Related Species Across the Nernst Diffusion Layer
50. Bear · 1972
51. Davies · 1972
52. Lide · 1995
53. Press · 1992
54. Nĕsić · Br. Corros. J. · 1997 · 32 · 26910.1179/bcj.1997.32.4.269 ↗
55. Parametric Study of CO2 Corrosion of Carbon Steel
56. Role of Conductive Corrosion Products on the Protectiveness of Corrosion Layers