journal article·2022-06

Simultaneous Incorporation of V and Mn Element into Polyanionic NASICON for High Energy‐Density and Long‐Lifespan Zn‐Ion Storage (Adv. Energy Mater. 23/2022)

Zeyi Wu, Fei Ye, Qiang Liu, Ruilvjing Pang, Yang Liu, Le Jiang, Zilong Tang, Linfeng Hu

Advanced Energy Materials· Volume 12· Issue 23
Publisher page

Abstract

Aqueous Zinc-ion Batteries In article number 2200654, Linfeng Hu and co-workers develop NASICON-typed V-Mn transition metal phosphate, Na4VMn(PO4)3, as a cathode material for robust aqueous Zn-ion storage. Taking advantage of its high-voltage properties that originate from the inductive effect and two-step electron transfer mechanism between V4+/V3+ and Mn3+/Mn2+ redox couple, the Na4VMn(PO4)3 cathode exhibits excellent overall battery performance with an energy density of 309.7 Wh kg−1, and good rate capacity and cycling stability (89.1% capacity retention after 3000 cycles).
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Research context

OpenAlex topics: Advanced battery technologies research · Conducting polymers and applications · Gas Sensing Nanomaterials and Sensors

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Affiliations

Department of Materials Science Fudan University Shanghai 200433 P. R. China

School of Materials Science and Engineering Southeast University Nanjing 211189 P. R. China

State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua University Beijing 100084 China

References

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