Highly Efficient (>9%) Lead‐Free AgBiS ₂ Colloidal Nanocrystal/Organic Hybrid Solar Cells

Abstract Environmentally friendly colloidal nanocrystals (NCs) are promising materials for next‐generation solar cells because of their low cost, solution processability, and facile bandgap tunability. Recently, silver bismuth disulfide (AgBiS ₂ ) has attracted considerable attention owing to its appreciable power conversion efficiency (PCE) of 6.4%. However, issues such as the low open‐circuit voltage ( V _OC ) compared to the bandgap of the AgBiS ₂ NCs and the unoptimized energy level structure at the AgBiS ₂ NC/PTB7 hole‐transporting layer (HTL) interface should be resolved to enhance the performance of solar cells. In this study, a design strategy to obtain efficient energy level structure in AgBiS ₂ NC/organic hybrid solar cells is proposed. By selecting PBDB‐T‐2F as an HTL with a lower highest occupied molecular orbital level than that of PTB7, the V _OC of the device is increased. Furthermore, iodide‐ and thiolate‐passivated AgBiS ₂ NC surfaces are generated using tetramethylammonium iodide (TMAI) and 2‐mercaptoethanol (2‐ME), which leads to the energy level optimization of NCs for efficient charge extraction. This improves the PCE from 3.3% to 7.1%. In addition, the polymer is replaced with a PBDB‐T‐2F:BTP‐4Cl blend to achieve a higher short‐circuit current density through complementary absorption. Accordingly, an AgBiS ₂ NC‐based solar cell with a PCE of 9.1% is fabricated.