Toward a Four‐Electron Redox Quinone Polymer for High Capacity Lithium Ion Storage

Abstract Despite recent advances, current polymeric organic cathode materials have failed to incorporate a high degree of lithium storage in a small molecular framework, resulting in low capacities relative to monomers. This report discloses the development of a lithium salt polymer of dihydroxyanthraquinone (LiDHAQS) capable of storing four Li⁺ per monomer. The combination of storing four Li⁺ per monomer and a low molecular weight monomer results in a capacity of 330 mA h g⁻¹, a record for this class of material. The additional redox events responsible for added Li⁺ storage occur between 3.0 and 3.6 V versus Li/Li⁺ resulting in an average discharge potential of 2.5 V versus Li/Li⁺. These metrics combined yield a high energy density of 825 W h kg⁻¹ which is a 55% improvement over commercial lithium cobalt oxide. The high performance of LiDHAQS makes it a promising material for next generation Li⁺ cathodes.