Porous FeCo Glassy Alloy as Bifunctional Support for High‐Performance Zn‐Air Battery

Abstract The Zn‐air battery (ZAB) is attracting increasing attention due to its high safety and preeminent performance. However, the practical application of ZAB relies heavily on developing durable support materials to replace conventional carbon supports which have unrecoverable corrosion issues, severely jeopardizing ZAB performance. Herein, a novel porous FeCo glassy alloy is developed as a bifunctional catalytic support for ZAB. The conducting skeleton of the porous glassy alloy is used to stabilize oxygen reduction cocatalysts, and more importantly, the FeCo serves as the primary phase for oxygen evolution. To demonstrate the concept of catalytic glassy alloy support, ultrasmall Pd nanoparticles are anchored, as oxygen reduction active sites, on the porous FeCo (noted as Pd/FeCo) for ZAB. The Pd/FeCo exhibits a significantly improved electrocatalytic activity for oxygen reduction (a half‐wave potential of 0.85 V) and oxygen evolution (a potential of 1.55 V to reach 10 mA cm⁻²) in the alkaline media. When used in the ZAB, the Pd/FeCo delivers an output power density of 117 mW cm⁻² and outstanding cycling stability for over 200 h (400 cycles), surpassing the conventional carbon‐supported Pt/C+IrO₂ catalysts. Such an integrated design that combines highly active components with a porous architecture provides a new strategy to develop novel nanostructured electrocatalysts.