Electronic “Bridge” Construction via Ag Intercalation to Diminish Catalytic Anisotropy for 2D Tin Diselenide Cathode Catalyst in Lithium–Oxygen Batteries

Abstract As cathode catalysts for lithium–oxygen batteries (LOBs), 2D materials are attracting significant attention due to their layered structures, tunable surface chemistry, and unique electronic states. However, catalytic anisotropy, particularly the poor catalytic capability of the van der Waals forces contained in stack edge planes, has suppressed the enhancement of LOB performance as 2D cathode catalysts. Here, an ion‐intercalation strategy is proposed to diminish the catalytic anisotropy of 2D materials. Ag ions are successfully intercalated into SnSe₂ layered structure and regulate the electronic states between stack edge planes, leading to an improvement in the catalytic capability of 2D SnSe₂. Notably, the catalytic capability of the 2D surface (001) plane of SnSe₂ is also significantly enhanced after Ag intercalation, which can efficiently accelerate charge transfer and suppress the passivation on the 2D surface plane during the oxygen reduction/evolution reaction process. As a consequence, the Ag‐intercalated SnSe₂ cathode exhibits superior specific capacity of 16871 mAh g⁻¹ and an ultrastable cycle life over 2300 h at a current density of 100 mA g⁻¹ and 144 cycles at current density of 1000 mA g⁻¹. This work provides insights into the modulation of the catalytic capabilities of 2D materials, which have significant potential for this application in LOBs.